Synthesis, crystal structure, and photophysical properties of mononuclear and dinuclear palladium BODIPY chromophores

被引：4

作者：

Gupta, Gajendra ^{[1
,3
]}

Lee, Junseong ^{[2
]}

Lee, Chang Yeon ^{[1
,3
]}

机构：

[1] Incheon Natl Univ, Innovat Ctr Chem Engn, Dept Energy & Chem Engn, Incheon, South Korea

[2] Chonnam Natl Univ, Dept Chem, Gwangju, South Korea

[3] Incheon Natl Univ, Innovat Ctr Chem Engn, Dept Energy & Chem Engn, Incheon 22012, South Korea

来源：

BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2023年 / 44卷 / 05期

关键词：

BODIPY; heavy atom effect; Pd complexes; photocatalysis; singlet oxygen; SINGLET OXYGEN; PHOTODYNAMIC THERAPY; DERIVATIVES; DESIGN; STATE; DYES;

D O I：

10.1002/bkcs.12673

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mononuclear and dinuclear palladium-centered boron dipyrromethene (BODIPY) complexes, HBDPPdI and BDPPd2I2, respectively, were synthesized by the direct insertion of a palladium source into iodine-substituted BODIPY chromophores. The molecular structures of both metal complexes were characterized using several analytical techniques, including single crystal x-ray diffraction, to find that Pd(0) is coordinated directly to the ligand through a Pd-C bond facilitated by the insertion reaction. The photophysical properties of these complexes were also detailed.

引用

页码：390 / 394

页数：5

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