Structure, morphology, composition, optical properties of CuO/NiO nanocomposite for electrochemical energy storage devices

被引:16
作者
Arulkumar, E. [1 ]
Shree, S. Shanthosh [1 ]
Thanikaikarasan, S. [1 ]
机构
[1] Saveetha Inst Med & Tech Sci, Saveetha Sch Engn, Dept Phys Sci, Chennai 602105, Tamil Nadu, India
关键词
CuO/NiO; Cyclic voltammetry; EIS; GCD; XRD; OXIDE; CUO; NANOSTRUCTURES; EVOLUTION; STRATEGY;
D O I
10.1016/j.rechem.2023.101087
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A CuO/NiO nanocomposite synthesized using a simple co-precipitation process was employed to produce a highperformance electrochemical supercapacitor. The crystal nature, particle, composition, chemical state, and optical properties were investigated using powder XRD, TEM, EDX, FTIR, XPS, and UV-visible spectroscopy respectively. The electrochemical properties of CV, GCD and EIS are measured in 1 M NaOH. At a 0.5 Ag- 1 current density, the CuO/NiO composites exhibit greater capacitance (290.56 Fg-1) when compared to the individual compounds of CuO (165.20 Fg-1) and NiO (190.34 Fg-1). After 2000 cycles the CuO/NiO electrode was excellent 90% of capacity retention. The Ragone plot discovers better energy density of 4.24Wh kg- 1 and power density of 10.67 kW kg- 1 were provided by the CuO/NiO nanocomposites. The maximal ionic conductivity for the CuO/NiO nanocomposite is 3.56 10-4 S/cm based on the Cole-Cole plot. Furthermore, galvanostatic charge-discharge (GCD), peak current, dielectric properties of dielectric constant and electric modulus are discussed in this work. These results have indicated that the CuO/NiO nanocomposite is an excellent material for supercapacitor electrode construction.
引用
收藏
页数:15
相关论文
共 50 条
[21]   Optical and electrochemical performance of electrospun NiO-Mn3O4 nanocomposites for energy storage applications [J].
Doroudkhani, Zahra Shoghi ;
Mazloom, Jamal ;
Ghaziani, Majedeh Mahinzad .
SCIENTIFIC REPORTS, 2025, 15 (01)
[22]   Fabrication of manganese oxide decorated copper oxide (MnO2/CuO) nanocomposite electrodes for energy storage supercapacitor devices [J].
Racik, Mohamed K. ;
Manikandan, A. ;
Mahendiran, M. ;
Prabakaran, P. ;
Madhavan, J. ;
Raj, M. Victor Antony .
PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2020, 119
[23]   Structure and electrochemical properties of CuO-ZnO nanocomposite produced by the one-step novel discharge process [J].
Bishwakarma, Harish ;
Kumar Das, Alok ;
Kumar, Pankaj ;
Kumar Singh, Purushottam ;
Awad, Mohamed M. .
JOURNAL OF TAIBAH UNIVERSITY FOR SCIENCE, 2023, 17 (01)
[24]   Dual optical properties of NiO-doped PVA nanocomposite films [J].
Shaalan, N. M. ;
Hanafy, T. A. ;
Rashad, M. .
OPTICAL MATERIALS, 2021, 119
[25]   Development of the PANI-CuO and PANI-CuO-GO Nanocomposite Architecture and Comparative Investigation of the Physicochemical, Optical and Electrochemical Properties Towards Supercapacitor Applications [J].
Patil, Priyanka G. ;
Langade, Krushna J. ;
Vyawahare, Sanjay K. .
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2024, :1900-1911
[26]   Synthesis of ternary ZnO/CuO/MnO nanocomposite with crystalline and optical properties [J].
Premkumar, H. ;
Perumal, R. .
OPTICAL MATERIALS, 2024, 149
[27]   Direct growth of NiO nanosheets on mesoporous TiN film for energy storage devices [J].
Lee, Jae Hun ;
Lim, Jung Yup ;
Lee, Chang Soo ;
Park, Jung Tae ;
Kim, Jong Hak .
APPLIED SURFACE SCIENCE, 2017, 420 :849-857
[28]   Amorphous NiO nanopyramids with superior electrochromic energy storage properties [J].
Shi, Yingdi ;
Zhang, Yong ;
Zheng, Yulei ;
Tang, Kai ;
Ke, Xiang ;
Li, Zirong ;
Tang, Jing ;
Hui, Zhenzhen ;
Ye, Longqiang .
CERAMICS INTERNATIONAL, 2024, 50 (24) :55839-55844
[29]   Construction of NiO/MnO2/CeO2 hybrid nanoflake for electrochemical energy storage arrays as platform for electrochemical energy storage [J].
Cui, Lihua ;
Cui, Jiewu ;
Zheng, Hongmei ;
Wang, Yan ;
Qin, Yongqiang ;
Shu, Xia ;
Liu, Jiaqin ;
Zhang, Yong ;
Wu, Yucheng .
JOURNAL OF POWER SOURCES, 2017, 361 :310-317
[30]   Three dimensional NiO nanonetwork electrode for efficient electrochemical energy storage application [J].
Joseph, Nikhitha ;
Shafi, P. Muhammed ;
Sethulakshmi, J. S. ;
Karthik, Raj ;
Bose, A. Chandra ;
Shim, Jae-Jin .
ELECTROCHIMICA ACTA, 2021, 399