Structure, morphology, composition, optical properties of CuO/NiO nanocomposite for electrochemical energy storage devices

被引:29
作者
Arulkumar, E. [1 ]
Shree, S. Shanthosh [1 ]
Thanikaikarasan, S. [1 ]
机构
[1] Saveetha Inst Med & Tech Sci, Saveetha Sch Engn, Dept Phys Sci, Chennai 602105, Tamil Nadu, India
关键词
CuO/NiO; Cyclic voltammetry; EIS; GCD; XRD; OXIDE; CUO; NANOSTRUCTURES; EVOLUTION; STRATEGY;
D O I
10.1016/j.rechem.2023.101087
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A CuO/NiO nanocomposite synthesized using a simple co-precipitation process was employed to produce a highperformance electrochemical supercapacitor. The crystal nature, particle, composition, chemical state, and optical properties were investigated using powder XRD, TEM, EDX, FTIR, XPS, and UV-visible spectroscopy respectively. The electrochemical properties of CV, GCD and EIS are measured in 1 M NaOH. At a 0.5 Ag- 1 current density, the CuO/NiO composites exhibit greater capacitance (290.56 Fg-1) when compared to the individual compounds of CuO (165.20 Fg-1) and NiO (190.34 Fg-1). After 2000 cycles the CuO/NiO electrode was excellent 90% of capacity retention. The Ragone plot discovers better energy density of 4.24Wh kg- 1 and power density of 10.67 kW kg- 1 were provided by the CuO/NiO nanocomposites. The maximal ionic conductivity for the CuO/NiO nanocomposite is 3.56 10-4 S/cm based on the Cole-Cole plot. Furthermore, galvanostatic charge-discharge (GCD), peak current, dielectric properties of dielectric constant and electric modulus are discussed in this work. These results have indicated that the CuO/NiO nanocomposite is an excellent material for supercapacitor electrode construction.
引用
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页数:15
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