A perspective on the role of anions in highly concentrated aqueous electrolytes

被引：108

作者：

Han, Jin ^{[1
,2
]}

Mariani, Alessandro ^{[1
,2
,4
]}

Passerini, Stefano ^{[1
,2
,3
]}

Varzi, Alberto ^{[1
,2
]}

机构：

[1] Helmholtz Inst Ulm HIU, Helmholtzstr 11, D-89081 Ulm, Germany

[2] Karlsruhe Inst Technol KIT, POB 3640, D-76021 Karlsruhe, Germany

[3] Univ Rome Sapienza, Chem Dept, Piazzale A Moro 5, I-00138 Rome, Italy

[4] ELETTRA Synchrotron Trieste, I-34012 Trieste, Italy

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2023年 / 16卷 / 04期

关键词：

IN-SALT ELECTROLYTE; SOLID-ELECTROLYTE; RENEWABLE ENERGY; SODIUM-AIR; WATER; LITHIUM; STABILITY; LIQUID; SUPERCAPACITORS; PERFORMANCE;

D O I：

10.1039/d2ee03682g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly concentrated aqueous electrolytes enable a wider electrochemical stability window and, thus, higher energy batteries compared to conventional dilute aqueous solutions. Multiple properties of the electrolyte, e.g., ionic interactions, solvation structure, ion transport, tendency to hydrolyze, and capability to form a solid electrolyte interphase, distinctly change when the salt concentration is increased and highly depend on the salt anion. This work aims at reviewing, discussing and rationalizing the role of the salt anion in these physical and chemical properties in order to provide perspective guidelines for future developments.

引用

页码：1480 / 1501

页数：22

共 130 条

[71] On the dissociation constant of ammonium: Effects of using an incorrect pK(a) in calculations of the ammonia concentration in animal cell cultures [J].

Martinelle, K ;

Haggstrom, L .

BIOTECHNOLOGY TECHNIQUES, 1997, 11 (08) :549-551

[72] CONTRASTING CONDUCTANCE-VISCOSITY RELATIONS IN LIQUID STATES OF VITREOUS AND POLYMER SOLID ELECTROLYTES [J].

MCLIN, M ;

ANGELL, CA .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (08) :2083-2086

[73] First-Principles Study on the Peculiar Water Environment in a Hydrate-Melt Electrolyte [J].

Miyazaki, Kasumi ;

Takenaka, Norio ;

Watanabe, Eriko ;

Iizuka, Shota ;

Yamada, Yuki ;

Tateyama, Yoshitaka ;

Yamada, Atsuo .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2019, 10 (20) :6301-6305

[74] Over 2 V Aqueous Sodium-Ion Battery with Prussian Blue-Type Electrodes [J].

Nakamoto, Kosuke ;

Sakamoto, Ryo ;

Sawada, Yuki ;

Ito, Masato ;

Okada, Shigeto .

SMALL METHODS, 2019, 3 (04)

[75] Water-in-Salt Electrolyte Enables Ultrafast Supercapacitors for AC Line Filtering [J].

Park, Jinwoo ;

Lee, Junyoung ;

Kim, Woong .

ACS ENERGY LETTERS, 2021, 6 (02) :769-777

[76] Manganese-cobalt hexacyanoferrate cathodes for sodium-ion batteries [J].

Pasta, Mauro ;

Wang, Richard Y. ;

Ruffo, Riccardo ;

Qiao, Ruimin ;

Lee, Hyun-Wook ;

Shyam, Badri ;

Guo, Minghua ;

Wang, Yayu ;

Wray, L. Andrew ;

Yang, Wanli ;

Toney, Michael F. ;

Cui, Yi .

JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (11) :4211-4223

[77] Fractional Walden Rule for Electrolytes in Supercooled Disaccharide Aqueous Solutions [J].

Paula Longinotti, M. ;

Corti, Horacio R. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (16) :5500-5507

[78] The solubility of lithium and sodium fluorides [J].

Payne, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1937, 59 :947-947

[79] THE ELECTROCHEMICAL-BEHAVIOR OF ALKALI AND ALKALINE-EARTH METALS IN NON-AQUEOUS BATTERY SYSTEMS - THE SOLID ELECTROLYTE INTERPHASE MODEL [J].

PELED, E .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1979, 126 (12) :2047-2051

[80] Reinforced potassium and ammonium storage of the polyimide anode in acetate-based water-in-salt electrolytes [J].

Qiu, Shen ;

Xu, Yunkai ;

Li, Xin ;

Sandstrom, Sean K. ;

Wu, Xianyong ;

Ji, Xiulei .

ELECTROCHEMISTRY COMMUNICATIONS, 2021, 122

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