A perspective on the role of anions in highly concentrated aqueous electrolytes

被引：93
作者：
Han, Jin [1 ,2 ]
Mariani, Alessandro [1 ,2 ,4 ]
Passerini, Stefano [1 ,2 ,3 ]
Varzi, Alberto [1 ,2 ]
机构：
[1] Helmholtz Inst Ulm HIU, Helmholtzstr 11, D-89081 Ulm, Germany
[2] Karlsruhe Inst Technol KIT, POB 3640, D-76021 Karlsruhe, Germany
[3] Univ Rome Sapienza, Chem Dept, Piazzale A Moro 5, I-00138 Rome, Italy
[4] ELETTRA Synchrotron Trieste, I-34012 Trieste, Italy
来源：
ENERGY & ENVIRONMENTAL SCIENCE | 2023年 / 16卷 / 04期
关键词：
IN-SALT ELECTROLYTE; SOLID-ELECTROLYTE; RENEWABLE ENERGY; SODIUM-AIR; WATER; LITHIUM; STABILITY; LIQUID; SUPERCAPACITORS; PERFORMANCE;
D O I：
10.1039/d2ee03682g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Highly concentrated aqueous electrolytes enable a wider electrochemical stability window and, thus, higher energy batteries compared to conventional dilute aqueous solutions. Multiple properties of the electrolyte, e.g., ionic interactions, solvation structure, ion transport, tendency to hydrolyze, and capability to form a solid electrolyte interphase, distinctly change when the salt concentration is increased and highly depend on the salt anion. This work aims at reviewing, discussing and rationalizing the role of the salt anion in these physical and chemical properties in order to provide perspective guidelines for future developments.
引用
收藏
页码：1480 / 1501
页数：22
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  • [51] A 62 m K-ion aqueous electrolyte
    Ko, Seongjae
    Yamada, Yuki
    Yamada, Atsuo
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2020, 116
  • [52] Lithium-salt monohydrate melt: A stable electrolyte for aqueous lithium-ion batteries
    Ko, Seongjae
    Yamada, Yuki
    Miyazaki, Kasumi
    Shimada, Tatau
    Watanabe, Eriko
    Tateyama, Yoshitaka
    Kamiya, Takeshi
    Honda, Tsunetoshi
    Akikusa, Jun
    Yamada, Atsuo
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2019, 104
  • [53] VISCOSITY OF WATER AT VARIOUS TEMPERATURES
    KORSON, L
    DROSTHAN.W
    MILLERO, FJ
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1969, 73 (01) : 34 - &
  • [54] A High-Voltage Aqueous Electrolyte for Sodium-Ion Batteries
    Kuehnel, Ruben-Simon
    Reber, David
    Battaglia, Corsin
    [J]. ACS ENERGY LETTERS, 2017, 2 (09): : 2005 - 2006
  • [55] Na3V2O2x(PO4)2F3-2x: a stable and high-voltage cathode material for aqueous sodium-ion batteries with high energy density
    Kumar, P. Ramesh
    Jung, Young Hwa
    Lim, Chek Hai
    Kim, Do Kyung
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (12) : 6271 - 6275
  • [56] Toward a low-cost high-voltage sodium aqueous rechargeable battery
    Lee, Myeong Hwan
    Kim, Sung Joo
    Chang, Donghee
    Kim, Jinsoo
    Moon, Sehwan
    Oh, Kyungbae
    Park, Kyu-Young
    Seong, Won Mo
    Park, Hyeokjun
    Kwon, Giyun
    Lee, Byungju
    Kang, Kisuk
    [J]. MATERIALS TODAY, 2019, 29 : 26 - 36
  • [57] High K-storage performance based on the synergy of dipotassium terephthalate and ether-based electrolytes
    Lei, Kaixiang
    Li, Fujun
    Mu, Chaonan
    Wang, Jianbin
    Zhao, Qing
    Chen, Chengcheng
    Chen, Jun
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (02) : 552 - 557
  • [58] Water-in-Salt Electrolyte for Potassium-Ion Batteries
    Leonard, Daniel P.
    Wei, Zhixuan
    Chen, Gang
    Du, Fei
    Ji, Xiulei
    [J]. ACS ENERGY LETTERS, 2018, 3 (02): : 373 - +
  • [59] Simultaneous measurements and modeling of the electrochemical impedance and the cyclic voltammetric characteristics of graphite electrodes doped with lithium
    Levi, MD
    Aurbach, D
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (23): : 4630 - 4640
  • [60] RECHARGEABLE LITHIUM BATTERIES WITH AQUEOUS-ELECTROLYTES
    LI, W
    DAHN, JR
    WAINWRIGHT, DS
    [J]. SCIENCE, 1994, 264 (5162) : 1115 - 1118
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