A perspective on the role of anions in highly concentrated aqueous electrolytes

被引：108

作者：

Han, Jin ^{[1
,2
]}

Mariani, Alessandro ^{[1
,2
,4
]}

Passerini, Stefano ^{[1
,2
,3
]}

Varzi, Alberto ^{[1
,2
]}

机构：

[1] Helmholtz Inst Ulm HIU, Helmholtzstr 11, D-89081 Ulm, Germany

[2] Karlsruhe Inst Technol KIT, POB 3640, D-76021 Karlsruhe, Germany

[3] Univ Rome Sapienza, Chem Dept, Piazzale A Moro 5, I-00138 Rome, Italy

[4] ELETTRA Synchrotron Trieste, I-34012 Trieste, Italy

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2023年 / 16卷 / 04期

关键词：

IN-SALT ELECTROLYTE; SOLID-ELECTROLYTE; RENEWABLE ENERGY; SODIUM-AIR; WATER; LITHIUM; STABILITY; LIQUID; SUPERCAPACITORS; PERFORMANCE;

D O I：

10.1039/d2ee03682g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly concentrated aqueous electrolytes enable a wider electrochemical stability window and, thus, higher energy batteries compared to conventional dilute aqueous solutions. Multiple properties of the electrolyte, e.g., ionic interactions, solvation structure, ion transport, tendency to hydrolyze, and capability to form a solid electrolyte interphase, distinctly change when the salt concentration is increased and highly depend on the salt anion. This work aims at reviewing, discussing and rationalizing the role of the salt anion in these physical and chemical properties in order to provide perspective guidelines for future developments.

引用

页码：1480 / 1501

页数：22

共 130 条

[1] From lithium to sodium: cell chemistry of room temperature sodium-air and sodium-sulfur batteries [J].

Adelhelm, Philipp ;

Hartmann, Pascal ;

Bender, Conrad L. ;

Busche, Martin ;

Eufinger, Christine ;

Janek, Juergen .

BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 2015, 6 :1016-1055

[2] Physicochemical and Electrochemical Properties of Water-in-Salt Electrolytes [J].

Amiri, Mona ;

Belanger, Daniel .

CHEMSUSCHEM, 2021, 14 (12) :2487-2500

[3] Parallel developments in aprotic and protic ionic liquids: Physical chemistry and applications [J].

Angell, C. Austen ;

Byrne, Nolene ;

Belieres, Jean-Philippe .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (11) :1228-1236

[4] High-Voltage and Super-Stable Aqueous Sodium-Zinc Hybrid Ion Batteries Enabled by Double Solvation Structures in Concentrated Electrolyte [J].

Ao, Huaisheng ;

Zhu, Weiduo ;

Liu, Mengke ;

Zhang, Wanqun ;

Hou, Zhiguo ;

Wu, Xiaojun ;

Zhu, Yongchun ;

Qian, Yitai .

SMALL METHODS, 2021, 5 (07)

[5] Energy storage and its use with intermittent renewable energy [J].

Barton, JP ;

Infield, DG .

IEEE TRANSACTIONS ON ENERGY CONVERSION, 2004, 19 (02) :441-448

[6] Water-in-salt electrolytes for aqueous lithium-ion batteries with liquidus temperatures below-10 °C [J].

Becker, Maximilian ;

Kuehnel, Ruben-Simon ;

Battaglia, Corsin .

CHEMICAL COMMUNICATIONS, 2019, 55 (80) :12032-12035

[7] FILMING MECHANISM OF LITHIUM-CARBON ANODES IN ORGANIC AND INORGANIC ELECTROLYTES [J].

BESENHARD, JO ;

WINTER, M ;

YANG, J ;

BIBERACHER, W .

JOURNAL OF POWER SOURCES, 1995, 54 (02) :228-231

[8]

Bockris JohnOM., 2000, Modern Electrochemistry 2A: Fundamentals of Electrodics, P1035, DOI [DOI 10.1007/0-306-47605-3_2, 10.1007/0-306-47605-3_2]

[9] Uncharted Waters: Super-Concentrated Electrolytes [J].

Borodin, Oleg ;

Self, Julian ;

Persson, Kristin A. ;

Wang, Chunsheng ;

Xu, Kang .

JOULE, 2020, 4 (01) :69-100

[10] Liquid Structure with Nano-Heterogeneity Promotes Cationic Transport in Concentrated Electrolytes [J].

Borodin, Oleg ;

Suo, Liumin ;

Gobet, Mallory ;

Ren, Xiaoming ;

Wang, Fei ;

Faraone, Antonio ;

Peng, Jing ;

Olguin, Marco ;

Schroeder, Marshall ;

Ding, Michael S. ;

Gobrogge, Eric ;

Cresce, Arthur von Wald ;

Munoz, Stephen ;

Dura, Joseph A. ;

Greenbaum, Steve ;

Wang, Chunsheng ;

Xu, Kang .

ACS NANO, 2017, 11 (10) :10462-10471

← 1 2 3 4 5 6 7 8 9 10 →