Rapid co-deposition of dopamine and polyethyleneimine triggered by CuSO4/H2O2 oxidation to fabricate nanofiltration membranes with high selectivity and antifouling ability

Membrane surface properties play important roles in the separation performance and fouling behavior during the membrane-based water treatment processes. Mussel-inspired polydopamine (PDA) layer with abundant functional groups can endow the membrane surface with increased hydrophilicity as well as extraordinary versatility and creative potential for further functionalization toward specific applications. However, the slow deposition rate still limits its application in membrane modification. In this study, rapid deposition of the PDA layer on the surface of the polysulfone membrane was realized by catalytic oxidation using CuSO4/H2O2. Meanwhile, polyethyleneimine (PEI) was introduced to co-deposit with PDA to obtain a hydrophilic, uniform, and electroneutral separation layer for the nanofiltration membrane. An optimized stoichiometry of modifiers and oxidants was obtained by UV-vis absorbance measurement. The membrane surface properties including surface morphology, roughness, chemical element compositions, wettability, and charge behavior before and after modification were characterized through various techniques. The optimized PDA/PEI modified membrane (a-Cu(15)-PDA/PEI) possessed higher MgCl2/NaCl and dye/salt selectivities as well as improved anti-fouling performance compared to the commercial NF-270 membrane. Furthermore, the Gaussian simulation combined with XPS analysis illustrated that the introduction of Cu2+/H2O2 accelerated the dopamine oxidation and facilitated the formation of CO quinoid structures, thus providing more reactive sites for the Schiff base reaction in the PDA/PEI co-deposition process. The results from this study provide theoretical foundations for improving nanofiltration membrane performances by PDA/PEI modification.