Interface Adsorption and Aggregation Behavior of Sulfonate-Based Anionic Silicone Surfactants in Aqueous Solution

被引：1
作者：
Meng, Lina [1 ]
Wang, Wenyu [2 ]
Li, Lei [1 ]
Feng, Shengyu [1 ]
机构：
[1] Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Educ, Jinan 250199, Shandong, Peoples R China
[2] Jinan Agr Prod Qual & Safety Ctr, Jinan 250000, Shandong, Peoples R China
来源：
CHEMPLUSCHEM | 2023年 / 88卷 / 05期
基金：
中国国家自然科学基金;
关键词：
aggregation behavior; interface adsorption; micro-dynamic; silicone surfactant; sulfonate-based; SODIUM DODECYL-SULFATE; CATIONIC GEMINI SURFACTANTS; IONIC LIQUIDS; MICELLE FORMATION; MICELLIZATION PARAMETERS; TRISILOXANE SURFACTANTS; WATER-REPELLENCY; THERMODYNAMICS; CONDUCTIVITY; CHLORIDE;
D O I：
10.1002/cplu.202300152
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of sulfonate silicone surfactants possessing different hydrophobic groups were synthesized. Their adsorption and thermodynamic parameters in aqueous solutions were investigated by surface tension measurements, conductivity, transmission electron microscopy (TEM) and dynamic light scattering (DLS). These sulfonate-based anionic silicone surfactants exhibit significant surface activity and can reduce the surface tension of water to 19.6 mN m(-1) at critical micelle concentration. The TEM and DLS results demonstrate that the three sulfonated silicone surfactants self-assemble into homogeneous sized vesicle-like aggregates in aqueous solution. Moreover, the size of the aggregates was determined to be in the range from 80 to 400 nm at 0.05 mol L-1.
引用
收藏
页数：9
相关论文
共 64 条
  • [11] Aggregation behavior of long-chain imidazolium ionic liquids in aqueous solution: Micellization and characterization of micelle microenvironment
    Dong, Bin
    Zhao, Xueyan
    Zheng, Liqiang
    Zhang, Jin
    Li, Na
    Inoue, Tohru
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 317 (1-3) : 666 - 672
  • [12] Surface adsorption and micelle formation of surface active ionic liquids in aqueous solution
    Dong, Bin
    Li, Na
    Zheng, Liqiang
    Yu, Li
    Inoue, Tohru
    [J]. LANGMUIR, 2007, 23 (08) : 4178 - 4182
  • [13] Oil coating on hydrophilic surfaces from emulsions and under shear flow
    Essafi, W
    Poulin, P
    Chiron, S
    Bavouzet, B
    [J]. LANGMUIR, 2004, 20 (01) : 123 - 128
  • [14] EFFECT OF THE NATURE OF COUNTERIONS ON THE SPHERE-TO-ROD TRANSITION IN CETYLTRIMETHYLAMMONIUM MICELLES
    GAMBOA, C
    RIOS, H
    SEPULVEDA, L
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (14) : 5540 - 5543
  • [15] ADSORPTION OF SMALL SILICONE POLYETHER SURFACTANTS AT THE AIR/WATER INTERFACE
    GENTLE, TE
    SNOW, SA
    [J]. LANGMUIR, 1995, 11 (08) : 2905 - 2910
  • [16] Estimation of micellization parameters of sodium dodecyl sulfate in water+1-butanol using the mixed electrolyte model for molar conductance
    Gunaseelan, K
    Ismail, K
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 258 (01) : 110 - 115
  • [17] AGGREGATION BEHAVIOR AND MICROSTRUCTURE OF CATIONIC TRISILOXANE SURFACTANTS IN AQUEOUS-SOLUTIONS
    HE, M
    LIN, Z
    SCRIVEN, LE
    DAVIS, HT
    SNOW, SA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (24) : 6148 - 6157
  • [18] Silicone surfactants - new developments
    Hill, RM
    [J]. CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2002, 7 (5-6) : 255 - 261
  • [19] Impact of Molecular Architecture on Surface Properties and Aqueous Stabilities of Silicone-Based Carboxylate Surfactants
    Huang, Yue
    Guo, Mengdong
    Tan, Jinglin
    Feng, Shengyu
    [J]. LANGMUIR, 2020, 36 (08) : 2023 - 2029
  • [20] Synthesis and Solution Behavior of Sulfonate-Based Silicone Surfactants with Specific, Atomically Defined Hydrophobic Tails
    Huang, Yue
    Guo, Mengdong
    Feng, Shengyu
    [J]. LANGMUIR, 2019, 35 (30) : 9785 - 9793
1234567