An update on chiral phosphoric acid organocatalyzed stereoselective reactions

被引：36

作者：

Jimenez, Eddy I. ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Circuito Exterior,Ciudad Univ, Mexico City 04510, Mexico

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 17期

关键词：

CATALYTIC ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; CONSTRUCTION; ATROPISOMERISM; DEAROMATIZATION; STEREOCENTERS; CONVERSION; ALCOHOLS; AMINES;

D O I：

10.1039/d3ob00212h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral Phosphoric Acids (CPAs) are a highly versatile class of Bronsted acid organocatalysts that have witnessed a surge in their use in asymmetric synthesis in recent years. Various new protocols, including photoredox, atroposelective, and multicomponent reactions, have been developed to expand the range of applications for these catalysts. This review specifically examines the use of standalone chiral phosphoric acids as organocatalysts in asymmetric syntheses from 2018 to 2022. It is important to note that this review excludes catalytic systems that utilize a combination of metal catalysts (or metal complexes) with chiral phosphoric acids. Furthermore, this review does not cover CPA derivatives, such as N-triflyl phosphoramides, chiral disulfonimides, or newly developed imidodiphosphate-type Bronsted acids.

引用

页码：3477 / 3502

页数：26

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