Luminescent terpyridine-based metallo-supramolecular systems: from design to applications

被引：20

作者：

Guo, Chenxing ^{[1
,2
]}

Su, Feng ^{[1
]}

Su, Pingru ^{[1
,2
]}

Yu, Xiujun ^{[1
]}

Li, Xiaopeng ^{[1
,3
]}

机构：

[1] Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518060, Peoples R China

[2] Shenzhen Univ, Sch Biomed Engn, Guangdong Key Lab Biomed Measurements & Ultrasound, Natl Reg Key Technol Engn Lab Med Ultrasound,Med S, Shenzhen 518060, Peoples R China

[3] Shenzhen Univ, Gen Hosp, Clin Med Acad, Shenzhen 518055, Peoples R China

来源：

SCIENCE CHINA-CHEMISTRY | 2023年 / 66卷 / 07期

基金：

中国国家自然科学基金;

关键词：

luminescence; metallo-supramolecules; terpyridine; coordination-driven self-assembly; supramolecular chemistry; AGGREGATION-INDUCED EMISSION; POST-ASSEMBLY MODIFICATION; MOLECULAR ARCHITECTURE; COORDINATION-COMPLEXES; MASS-SPECTROMETRY; FLUORESCENCE; BINDING; GUEST; METALLACYCLES; METALLACAGES;

D O I：

10.1007/s11426-023-1601-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Luminescent metallo-supramolecules have received tremendous attention in recent years owing to their diverse yet well-defined structures, tunable luminescent properties, and broad applications. In this context, the development of terpyridine (tpy)-based luminescent metallo-supramolecular systems has seen rapid growth. This review aims to summarize the recent progress of luminescent metallo-supramolecular assemblies from tpy ligands with metal ions, with a focus on discrete metallo-supramolecular architectures and metallo-supramolecular polymers. The design strategies and common approaches for tuning the luminescence properties are detailed along with representative applications. Finally, the pitfalls and unmet challenges regarding the structural characterization and practical applications of tpy-based metallo-supramolecules are discussed followed by our perspectives on the future directions of this field.

引用

页码：1940 / 1962

页数：23

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