Phase Separation in the Double Perovskite Sr2FeNbO6-δ

被引:3
|
作者
Popov, Daniil [1 ]
Batulin, Ruslan [2 ]
Cherosov, Mikhail [2 ]
Vagizov, Farit [2 ]
Zinnatullin, Almaz [2 ]
Chupakhina, Tatiana [3 ]
Deeva, Yuliya [3 ]
Maiti, Tanmoy [4 ]
Eremina, Rushana [1 ]
机构
[1] RAS, Kazan Sci Ctr, Fed Res Ctr, Zavoisky Phys Tech Inst, Kazan 420029, Russia
[2] Kazan Volga Reg Fed Univ, Inst Phys, Kazan 420008, Russia
[3] Russian Acad Sci UB, Inst Solid State Chem, Ekaterinburg 620990, Russia
[4] Indian Inst Technol, Dept Mat Sci & Engn, Kanpur 208016, Uttar Pradesh, India
基金
俄罗斯科学基金会;
关键词
Mossbauer spectra; specific heat capacity; double perovskite; MAGNETIC-PROPERTIES; MOSSBAUER-SPECTRA; OXIDE;
D O I
10.3390/magnetochemistry9100219
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The ceramic perovskite Sr2FeNbO6-delta was synthesized via the solution combustion precursor method. X-ray phase analysis showed that the sample is single-phase and does not contain impurities. The specific heat capacity and the Mossbauer spectra were measured for the Sr2FeNbO6-delta ceramic in the temperature range of 4-300 K. The observation of an asymmetric doublet in the Mossbauer spectra and the literature data on the magnetic susceptibility indicated the presence of two magnetic subsystems in Sr2FeNbO6-delta with antiferromagnetic exchange interactions. Based on the analysis of the temperature dependence of the specific heat capacity, we determined the Debye and Einstein temperatures.
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页数:14
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