Hydrogen Production Properties of Aluminum-Magnesium Alloy Presenting β-Phase Al3Mg2

被引:4
|
作者
Cuzacq, Laurent [1 ]
Polido, Chloe [1 ]
Silvain, Jean-Francois [1 ,2 ]
Bobet, Jean-Louis [1 ]
机构
[1] Univ Bordeaux, Dept Chem, CNRS, Bordeaux INP,ICMCB,UMR 5026, F-33600 Pessac, France
[2] Univ Nebraska, Dept Elect & Comp Engn, Lincoln, NE 68588 USA
关键词
Al-Mg alloys; intermetallic phases; uniaxial hot pressing; hydrogen production; hydrolysis; HYDROLYSIS; ENERGY; GENERATION; COMPOSITES; MG;
D O I
10.3390/met13111868
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, aluminum-magnesium (Al-Mg) bulk porous materials were fabricated by using uniaxial hot pressing to control the porosity rate of the material over a wide range (up to 50%). The fabricated materials were analyzed by X-ray diffraction and scanning electron microscopy. The results demonstrated the appearance of intermetallic (IM) phase Al3Mg2, and its quantity increased with the applied pressure. In the context of the decline of global fossil fuel reserves, the revalorization of these materials by hydrogen (H-2) production was investigated. Hydrolysis of the Al-Mg materials was carried out in a simulated seawater solution (aqueous solution of sodium chloride 35 g/L). The results showed the role of the porosity rate in the H(2 )production properties of the fabricated materials; the increase of porosity rate from 10% to 50% cuts the reaction time in half. Finally, the role of IM phase Al(3)Mg(2 )in H(2 )production was highlighted through galvanic coupling.
引用
收藏
页数:10
相关论文
共 50 条
  • [1] Evaluation of Al3Mg2 Precipitates and Mn-Rich Phase in Aluminum-Magnesium Alloy Based on Scanning Transmission Electron Microscopy Imaging
    Zhu, Yakun
    Cullen, David A.
    Kar, Soumya
    Free, Michael L.
    Allard, Lawrence F.
    METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2012, 43A (13): : 4933 - 4939
  • [2] Wetting of grain boundaries in Al by the solid Al3Mg2 phase
    Straumal, B. B.
    Baretzky, B.
    Kogtenkova, O. A.
    Straumal, A. B.
    Sidorenko, A. S.
    JOURNAL OF MATERIALS SCIENCE, 2010, 45 (08) : 2057 - 2061
  • [3] High Temperature Oxidation of the Al3Mg2 Complex Metallic Alloy
    M.-N. de Noirfontaine
    G. Baldinozzi
    M.-G. Barthés-Labrousse
    J. Kusinski
    G. Boëmare
    M. Herinx
    M. Feuerbacher
    Oxidation of Metals, 2010, 73 : 219 - 232
  • [4] High Temperature Oxidation of the Al3Mg2 Complex Metallic Alloy
    de Noirfontaine, M. -N.
    Baldinozzi, G.
    Barthes-Labrousse, M. -G.
    Kusinski, J.
    Boemare, G.
    Herinx, M.
    Feuerbacher, M.
    OXIDATION OF METALS, 2010, 73 (1-2): : 219 - 232
  • [5] Microstructure and hydrogen production of the rapidly solidified Al-Mg-Ga-In-Sn alloy
    He, Tiantian
    Chen, Wei
    Wang, Wei
    Du, Sanming
    Deng, Sier
    JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 827 (827)
  • [6] Investigation of rolling modes, structure, and properties of aluminum-magnesium alloy plates with a reduced scandium content
    Sidelnikov, Sergey Borisovich
    Baranov, Vladimir Nikolaevich
    Konstantinov, Igor Lazarevich
    Zenkin, Evgeniy Yuryevich
    Lopatina, Ekaterina Sergeevna
    Bezrukikh, Aleksandr Innokentyevich
    Voroshilov, Denis Sergeevich
    Yuryev, Pavel Olegovich
    Mansurov, Yulbarskhon Nabievich
    Voroshilova, Marina Vladimirovna
    Belokonova, Irina Nikolaevna
    Galiev, Roman Ilsurovich
    INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY, 2022, 121 (1-2) : 1373 - 1384
  • [7] Hardness and Wear Properties of Al-4.5%Cu/Al3Mg2 Nanocomposite Prepared by Mechanical Alloying
    Nemati, Narguess
    Emamy, Massoud
    Emami, Ali Reza
    Mashhoodi, Mashhood
    MATERIALS TRANSACTIONS, 2012, 53 (07) : 1310 - 1317
  • [8] Hydrogen Production Behavior of Al-Mg-Ga-Sn Alloy in Seawater
    Zhang Jianbin
    Jiao Kai
    Gao Jiji
    Rong Yu
    Shi Yu
    RARE METAL MATERIALS AND ENGINEERING, 2020, 49 (10) : 3582 - 3589
  • [9] Hydrogen Induced Debonding of Mg 2 Si Particle / Aluminum Interface in Al-Mg-Si Alloy
    Toda, Hiroyuki
    Fujihara, Hiro
    Hirayama, Kyosuke
    Shimizu, Kazuyuki
    Wang, Yafei
    Bhupendra, Sharma
    Tang, Jianwei
    Takeuchi, Akihisa
    Uesugi, Masayuki
    MATERIALS TRANSACTIONS, 2024, 65 (07) : 763 - 772
  • [10] New Organic/Inorganic Pigments Based on Azo Dye and Aluminum-Magnesium Hydroxycarbonates with Various Mg/Al Ratios
    Marzec, Anna
    Szadkowski, Boleslaw
    Rogowski, Jacek
    Maniukiewicz, Waldemar
    Rybinski, Przemyslaw
    Prochon, Miroslawa
    MATERIALS, 2019, 12 (08)