Controlled growth and spectroscopy characterization of blue violet perovskite quantum dots in borate glasses

被引：6

作者：

Lin, Mengqi ^{[1
]}

Zhang, Xizhen ^{[1
]}

Dong, Yabo ^{[1
]}

Xu, Sai ^{[1
]}

Li, Xiangping ^{[1
]}

Yu, Hongquan ^{[1
]}

Sun, Jiashi ^{[1
]}

Cheng, Lihong ^{[1
]}

Chen, Baojiu ^{[1
]}

机构：

[1] Dalian Maritime Univ, Sch Sci, Dalian 116026, Peoples R China

来源：

CERAMICS INTERNATIONAL | 2023年 / 49卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Perovskite quantum dots glasses; Blue violet light; Exciton emission; Controlled growth; Wavelength adjustment; Reabsorption; ROOM-TEMPERATURE; CSPBX3; X; BR; CL; NANOCRYSTALS; LUMINESCENT; PERFORMANCE; STABILITY; EMISSION; CSPBBR3;

D O I：

10.1016/j.ceramint.2023.03.151

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Blue violet light emitting CsPb(Cl/Br)3 perovskite quantum dots glasses (QDGs) have been successfully fabricated in multi-component borate glass matrix by melt quenching and heat treatment. The spectral characteristics have been evaluated by photoluminescence (PL), PL excitation (PLE), PL decay and absorption spectra. The recipe and preparation conditions have been optimized for controlled growth of QDs. By using raw materials of NH4Br/ NH4Cl/PbO and crucible cover, optimizing composition of Na2O/K2O in matrix, melting temperature and time, heat treatment temperature and time, and NH4Cl and NH4Br contents, we have finally realized blue violet exciton emission in target range of 405-440 nm. The PL wavelength adjustment is comprehensive effect of the abovementioned influence factors. The emission in short wavelength of 405-440 nm is due to controlled growth of the QDs. In final CsPb(Cl/Br)3 QDs, the contents of Cl and Br are suitable and the Cl/Br ratios are large. A little Br is necessary for growth of CsPb(Cl/Br)3 QDs and then the Br is partially replaced by Cl at suitable treatment condition. Unsymmetrical PL spectrum profile of some samples is explained as reabsorption effect by monitoring PL spectral profile and PL decay. The temperature characteristics of PL spectra show good recoverability after a temperature cycle.

引用

页码：20281 / 20289

页数：9

共 41 条

[1] Highly stable, luminescent core-shell type methylammonium-octylammonium lead bromide layered perovskite nanoparticles [J].

Bhaumik, Saikat ;

Veldhuis, Sjoerd A. ;

Ng, Yan Fong ;

Li, Mingjie ;

Muduli, Subas Kumar ;

Sum, Tze Chien ;

Damodaran, Bahulayan ;

Mhaisalkar, Subodh ;

Mathews, Nripan .

CHEMICAL COMMUNICATIONS, 2016, 52 (44) :7118-7121

[2] ELECTRON ELECTRON AND ELECTRON-HOLE INTERACTIONS IN SMALL SEMICONDUCTOR CRYSTALLITES - THE SIZE DEPENDENCE OF THE LOWEST EXCITED ELECTRONIC STATE [J].

BRUS, LE .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (09) :4403-4409

[3] Promoting photoluminescence quantum yields of glass-stabilized CsPbX3 (X = Cl, Br, I) perovskite quantum dots through fluorine doping [J].

Chen, Daqin ;

Liu, Yue ;

Yang, Changbin ;

Zhong, Jiasong ;

Zhou, Su ;

Chen, Jiangkun ;

Huang, Hai .

NANOSCALE, 2019, 11 (37) :17216-17221

[4] Robust CsPbX3 (X = Cl, Br, and I) perovskite quantum dot embedded glasses: nanocrystallization, improved stability and visible full-spectral tunable emissions [J].

Chen, Daqin ;

Yuan, Shuo ;

Chen, Jiangkun ;

Zhong, Jiasong ;

Xu, Xuhui .

JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (47) :12864-12870

[5]

Chen DQ, 2018, J MATER CHEM C, V6, P6832, DOI [10.1039/c8tc02407c, 10.1039/C8TC02407C]

[6] Efficient and bright white light-emitting diodes based on single-layer heterophase halide perovskites [J].

Chen, Jiawei ;

Wang, Jian ;

Xu, Xiaobao ;

Li, Jinhang ;

Song, Jizhong ;

Lan, Si ;

Liu, Sinan ;

Cai, Bo ;

Han, Boning ;

Precht, Jake T. ;

Ginger, David ;

Zeng, Haibo .

NATURE PHOTONICS, 2021, 15 (03) :238-244

[7]

Chukwuocha E.O., 2012, WORLD J CONDENS MAT, V2, P96, DOI [DOI 10.4236/WJCMP.2012.22017, 10.4236/wjcmp.2012.22017]

[8] Use of long-term stable CsPbBr3 perovskite quantum dots in phospho-silicate glass for highly efficient white LEDs [J].

Di, Xiaoxuan ;

Hu, Zemin ;

Jiang, Jutao ;

He, Meiling ;

Zhou, Lei ;

Xiang, Weidong ;

Liang, Xiaojuan .

CHEMICAL COMMUNICATIONS, 2017, 53 (80) :11068-11071

[9] Eu3+doped CsPbCl2Br1 nanocrystals glass for enhanced the ultraviolet response of Si photodetectors [J].

Ding, Jing ;

Mu, Shouying ;

Xiang, Weidong ;

Ding, Nan ;

Xu, Wen ;

Liang, Xiaojuan .

JOURNAL OF LUMINESCENCE, 2023, 254

[10] Extremely efficient quantum-cutting Cr3+, Ce3+, Yb3+ tridoped perovskite quantum dots for highly enhancing the ultraviolet response of Silicon photodetectors with external quantum efficiency exceeding 70% [J].

Ding, Nan ;

Xu, Wen ;

Zhou, Donglei ;

Ji, Yanan ;

Wang, Yue ;

Sun, Rui ;

Bai, Xue ;

Zhou, Ji ;

Song, Hongwei .

NANO ENERGY, 2020, 78

← 1 2 3 4 5 →