Grafting of Maleic Anhydride onto Poly(vinylidene fluoride) Using Reactive Extrusion

被引:2
作者
Zhang, Cuichuan [1 ]
Lu, Zhiqiang [1 ]
Wu, Bin [1 ]
Jiang, Shu-Dong [1 ]
Qian, Jiasheng [1 ]
机构
[1] Anhui Univ, Sch Chem & Chem Engn, Key Lab Environm Friendly Polymer Mat Anhui Prov, Hefei 230601, Peoples R China
来源
MOLECULES | 2023年 / 28卷 / 05期
关键词
PVDF; MAH; stem grafting; melt extrusion; PVDF MEMBRANE; COMPOSITES; COPOLYMERIZATION; MORPHOLOGY; BLENDS;
D O I
10.3390/molecules28052246
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Poly(vinylidene fluoride) was grafted with maleic anhydride through reactive extrusion by using diisopropyl benzene peroxide as an initiator and 9-vinyl anthracene as a stabilizer. Effects of various parameters on grafting degree were investigated including the amounts of monomer, initiator and stabilizer. The maximum extent of grafting achieved was 0.74%. The graft polymers were characterized using FTIR, water contact angle, thermal, mechanical and XRD studies. Improved hydrophilic and mechanical properties were observed for graft polymers.
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页数:11
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