Rhenium complex-catalyzed N-allylation and N-benzylation of amines with alcohols

被引：4

作者：

Umeda, Rui ^{[1
]}

Shimaoka, Shiori ^{[1
]}

Mori, Shintaro ^{[1
]}

Takagishi, Tsubasa ^{[1
]}

Nishiyama, Yutaka ^{[1
]}

机构：

[1] Kansai Univ, Fac Chem Mat & Bioengn, Suita, Osaka 5648680, Japan

来源：

TETRAHEDRON LETTERS | 2023年 / 119卷

关键词：

Rhenium; Allylation benzylation; Alcohols; Amines; ALLYLIC ALCOHOLS; ENOL ACETATES; PALLADIUM; AMINATION; ALKYLATION; TRANSPOSITION; BONDS; OXIDE;

D O I：

10.1016/j.tetlet.2023.154412

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

When aliphatic amines were allowed to react with allylic alcohols in the presence of a catalytic amount of a rhenium complex, the N-allylation of aliphatic amines efficiently proceeded to give the corresponding N-allyl substituted amines in moderate to good yields. Similarly, the N-benzylation of an amine with ben-zylic alcohols occurred in the presence of the rhenium catalyst. (c) 2023 Elsevier Ltd. All rights reserved.

引用

页数：4

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