Study on the Impact of a Combination of Synthetic Wollastonite and 2-Mercaptobenzothiazole-Based Fillers on UHMWPE Polymeric Matrix

被引:5
作者
Danilova, Sakhayana N. [1 ]
Okhlopkova, Aitalina A. [1 ]
Yarusova, Sofia B. [2 ,3 ]
Dyakonov, Afanasy A. [1 ]
Gordienko, Pavel S. [2 ]
Papynov, Evgeniy K. [4 ]
Shichalin, Oleg O. [4 ]
Buravlev, Igor Yu. [4 ]
Vasilev, Andrey P. [1 ]
Zhevtun, Ivan G. [2 ]
Ivanenko, Natalya V. [5 ]
机构
[1] North Eastern Fed Univ, Inst Nat Sci, Chem Dept, Yakutsk 677000, Russia
[2] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia
[3] Vladivostok State Univ, Dept Ecol & Environm Problems Chem Technol, Vladivostok 690014, Russia
[4] Far Eastern Fed Univ, Dept Nucl Technol, Vladivostok 690922, Russia
[5] Vladivostok State Univ, Dept Ecol Biol & Geog, Vladivostok 690014, Russia
关键词
polymer composite materials; ultra-high molecular weight polyethylene; wollastonite; 2-mercaptobenzothiazole; MOLECULAR-WEIGHT POLYETHYLENE; WEAR BEHAVIOR; MECHANISM; COMPOSITES; CRYSTAL; NANOPARTICLES; NANOFILLER; ACTIVATION; DISPERSION; SPECTRA;
D O I
10.3390/jcs7100431
中图分类号
TB33 [复合材料];
学科分类号
摘要
This study investigates the impact of a binary filler on the physicomechanical and tribological properties, as well as structure, of polymeric composite materials based on ultra-high-molecular-weight polyethylene. The organic modifier-2-mercaptobenzothiazole and wollastonite particles synthesized from two different systems (modeled and derived from waste) were used as the binary filler. The synthesis of wollastonite was carried out in the complex model system (CaSO4 center dot 2H2O-SiO2 center dot nH2O-KOH-H2O) and from technogenic waste (borogypsum). It was demonstrated that the introduction of the binary filler made it possible to obtain an optimal combination of mechanical and tribological properties. It was found that during the wear of polymeric composite materials loaded with organic fillers, the fillers migrate to the friction surface, providing a shield against abrasive wear of the steel counterface. Due to the modification of ultra-high-molecular-weight polyethylene by 2-mercaptobenzothiazole, the interdiffusion of polymeric matrix macromolecules and interphase coupling with wollastonite particles improve. The 2-mercaptobenzothiazole organic compound used as the filler facilitates the relaxation processes within the composite under external loads.
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页数:20
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