Electrochemical performance of SnO2/C nanocomposites as anode materials for lithium-ion batteries

被引:7
作者
Fan, Yingqiang [1 ]
Chen, Xiujuan [2 ]
Zhang, Laixi [2 ]
Wu, Jiakui [1 ]
Wang, Linlin [1 ]
Yu, Shurong [2 ]
Wu, Mingliang [2 ]
机构
[1] Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
[2] Lanzhou Univ Technol, Sch Mech & Elect Engn, Lanzhou 730050, Peoples R China
关键词
SnO2; Carbon coating; Anode material; Lithium-ion battery; Hydrothermal synthesis; HIGH-CAPACITY; CARBON FRAMEWORK; COMPOSITE; STORAGE; NANOCRYSTALS; NANOSPHERES; NANOFIBERS; NANOTUBES;
D O I
10.1007/s11581-022-04806-x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carbon-coated SnO2 nanocomposites were synthesized successfully by the hydrothermal method and carbonization at 500 degrees C with glucose and SnCl2?2H(2)O as precursor materials. The SnO2/C nanocomposites were characterized by various techniques such as X-ray powder diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), Raman spectra, and electrochemical analyses. It was demonstrated that SnO2/C-0, SnO2/C-5, SnO2/C-15, SnO2/C-30, and SnO2/C-50 had initial discharge capacities of 1359.2, 1626.8, 2124.9, 1525.8, and 1349.4 mAhg-1, respectively. In particular, the SnO2/C-15 sample exhibited excellent high reversible lithium storage capacity, good rate capability, and cycling stability. The electrodes show a long cycling ability and high charge/discharge capacity due to the presence of carbon.
引用
收藏
页码:497 / 504
页数:8
相关论文
共 40 条
[1]   Self-Standing Carbon Nanofiber and SnO2 Nanorod Composite as a High-Capacity and High-Rate-Capability Anode for Lithium-Ion Batteries [J].
Abe, Jyunichiro ;
Takahashi, Keisuke ;
Kawase, Koki ;
Kobayashi, Yuta ;
Shiratori, Seimei .
ACS APPLIED NANO MATERIALS, 2018, 1 (06) :2982-2989
[2]   Ultrafine SnO2 nanoparticles encapsulated in ordered mesoporous carbon framework for Li-ion battery anodes [J].
Abouali, Sara ;
Akbari Garakani, Mohammad ;
Kim, Jang-Kyo .
ELECTROCHIMICA ACTA, 2018, 284 :436-443
[3]  
Chao Z, 2021, CHEM PHYS LETT, V772
[4]   Nanofibers Comprising Yolk-Shell Sn@void@SnO/SnO2 and Hollow SnO/SnO2 and SnO2 Nanospheres via the Kirkendall Diffusion Effect and Their Electrochemical Properties [J].
Cho, Jung Sang ;
Kang, Yun Chan .
SMALL, 2015, 11 (36) :4673-4681
[5]   Self-sacrificing template method to controllable synthesize hollow SnO2@C nanoboxes for lithium-ion battery anode [J].
Dai, Qingshan ;
Gu, Cuiping ;
Xu, Yayun ;
Zhang, Yang ;
Hong, Yong ;
Joo, Sang Woo ;
Huang, Jiarui .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2021, 898
[6]   Recent advances in cathode prelithiation additives and their use in lithium-ion batteries [J].
Ding, Ruqian ;
Tian, Shiyu ;
Zhang, Kaicheng ;
Cao, Jingrui ;
Zheng, Yi ;
Tian, Weichao ;
Wang, Xiaoyan ;
Wen, Lizhi ;
Wang, Li ;
Liang, Guangchuan .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2021, 893
[7]   Microwave-Assisted Synthesis of SnO2@polypyrrole Nanotubes and Their Pyrolyzed Composite as Anode for Lithium-Ion Batteries [J].
Du, Xianfeng ;
Yang, Tongjia ;
Lin, Jun ;
Feng, Tianyu ;
Zhu, Jianbo ;
Lu, Lu ;
Xu, Youlong ;
Wang, Jingping .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (24) :15598-15606
[8]   Oxalate-assisted formation of uniform carbon-confined SnO2 nanotubes with enhanced lithium storage [J].
Han, Chunhua ;
Zhang, Baoxuan ;
Zhao, Kangning ;
Meng, Jiashen ;
He, Qiu ;
He, Pan ;
Yang, Wei ;
Li, Qi ;
Mai, Liqiang .
CHEMICAL COMMUNICATIONS, 2017, 53 (69) :9542-9545
[9]   Sonochemistry-enabled uniform coupling of SnO2 nanocrystals with graphene sheets as anode materials for lithium-ion batteries [J].
Han, Xiaoyan ;
Li, Ran ;
Qiu, Shengqiang ;
Zhang, Xiaofang ;
Zhang, Qing ;
Yang, Yingkui .
RSC ADVANCES, 2019, 9 (11) :5942-5947
[10]   Nitrogen-doped carbon coated SnO2 nanoparticles embedded in a hierarchical porous carbon framework for high-performance lithium-ion battery anodes [J].
Hong, Ye ;
Mao, Wenfeng ;
Hu, Qianqian ;
Chang, Shiyong ;
Li, Dejun ;
Zhang, Jingbo ;
Liu, Gao ;
Ai, Guo .
JOURNAL OF POWER SOURCES, 2019, 428 :44-52