Preparation of mesoporous TiO2 nanomaterials doped with rare earth ions (La3+, Sm3+, Nd3+, Gd3+) and its application in the photodegradation of unsymmetrical dimethylhydrazine wastewater

被引：1

作者：

Zeng, Yizhi ^{[1
]}

Ren, Xianghong ^{[1
]}

机构：

[1] Xian Res Inst Hitech, Xian 710025, Peoples R China

来源：

GLOBAL NEST JOURNAL | 2023年 / 25卷 / 10期

关键词：

mesoporous TiO2; degradation; unsymmetrical dimethylhydrazine; PHOTOCATALYTIC ACTIVITY; N-NITROSODIMETHYLAMINE; NANOPARTICLES; DEGRADATION; PERFORMANCE; OXIDATION;

D O I：

10.30955/gnj.005280

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Unsymmetrical dimethylhydrazine (UDMH) and its byproducts cause serious damage to human health. In this paper, Re3+-doped mesoporous TiO2 were synthesized for the photodegradation of UDMH. The structure, morphology and optical properties of photocatalyst were extensively characterized. The photocatalytic degradation was significantly enhanced, and 2%Nd-TiO2 showed the most excellent photocatalytic degradation performance with 93.3% degradation rate of UDMH. NDMA and FDMH were gradually and completely degraded. center dot O2- and center dot OH played an important role in the photocatalytic degradation of UDMH. The work provided an effective method for the degradation of UDMH wastewater.

引用

页码：81 / 92

页数：12

共 33 条

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[9] Studies on structural, morphological and electrical properties of Ce0.8Ln0.2O2-δ (Ln = Y3+, Gd3+, Sm3+, Nd3+ and La3+) solid solutions prepared by citrate complexation method
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[10] Preparation, characterization, and photocatalytic activity of Gd3+ doped TiO2 nanoparticles
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