Pr3Mo4B6O24(OH)3: High-Pressure/High-Temperature Synthesis of an Acentric Rare Earth Molybdenum Borate

被引：2

作者：

Teichtmeister, Tobias A. ^{[1
]}

Bayarjargal, Lkhamsuren ^{[2
]}

Wurst, Klaus ^{[1
]}

Heymann, Gunter ^{[1
]}

Huppertz, Hubert ^{[1
]}

机构：

[1] Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, Innrain 80-82, A-6020 Innsbruck, Austria

[2] Goethe Univ Frankfurt, Inst Geowissensch, Altenhoferallee 1, D-60438 Frankfurt, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 26卷 / 05期

关键词：

Borates; High-pressure chemistry; Multianvil; Rare earths; Structure elucidation; CRYSTAL-STRUCTURE; STRUCTURE VALIDATION; VIBRATIONAL-SPECTRA; PHOSPHOR; LUMINESCENCE; BOND; DISTANCES; IR; LA;

D O I：

10.1002/ejic.202200635

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report on the synthesis of a new praseodymium molybdenum borate under high-pressure/high-temperature conditions. The new compound with the sum formula Pr3Mo4B6O24(OH)(3) crystallizes acentrically in the monoclinic space group Cm displaying a new structure type. The structure was solved via single-crystal structure determination. Additionally, the proposed structural model was confirmed by powder X-ray diffraction, second harmonic generation measurement, and single-crystal infrared and Raman spectroscopic investigation.

引用

页数：9

共 72 条

[1] ON THE CRYSTAL STRUCTURE OF MOLYBDENUM TRIOXIDE [J].