Enthalpy of Sublimation of Organic and Metal-Organic Compounds: Influence of the Polarization Effect

被引：3

作者：

Khamaletdinova, N. M. ^{[1
]}

Kuznetsova, O. V. ^{[1
]}

Egorochkin, A. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2023年 / 64卷 / 04期

关键词：

enthalpy of sublimation; correlation analysis; classical electronic effects; polarization effect; VAPOR-PRESSURES; PARAMETERS; COMPLEXES;

D O I：

10.1134/S0022476623040108

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The published data on the enthalpy of sublimation Delta H-sub for 13 series of organic and metal-organic compounds are considered using the correlation analysis. Each series has a fixed reaction center and variable substituents. It is shown for the first time that Delta H-sub values depend not only on the classical inductive, resonance, and steric effects, but also on the polarization effect of substituents. In some series, the polarization effect has a major influence on Delta H-sub.

引用

页码：624 / 630

页数：7

共 17 条

[1] Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2010 [J].

Acree, William, Jr. ;

Chickos, James S. .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 2010, 39 (04)

[2]

Draper N. R., 1998, Applied Regression Analysis

[3] Mossbauer parameters of organometallic compounds and polarizability effect [J].

Egorochkin, Alexey N. ;

Kuznetsova, Olga V. ;

Khamaletdinova, Nadiya M. ;

Domratcheva-Lvova, Lada G. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2012, 710 :12-19

[4] NQR parameters of complexes and polarizability effect [J].

Egorochkin, Alexey N. ;

Kuznetsova, Olga V. ;

Khamaletdinova, Nadiya M. ;

Domratcheva-Lvova, Lada G. .

MAGNETIC RESONANCE IN CHEMISTRY, 2012, 50 (01) :40-51

[5] Review of Sublimation Thermodynamics of Polycyclic Aromatic Compounds and Heterocycles [J].

Goldfarb, Jillian L. .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 2013, 50 (06) :1243-1263

[6] A SURVEY OF HAMMETT SUBSTITUENT CONSTANTS AND RESONANCE AND FIELD PARAMETERS [J].

HANSCH, C ;

LEO, A ;

TAFT, RW .

CHEMICAL REVIEWS, 1991, 91 (02) :165-195

[7] A SCALE OF DIRECTIONAL SUBSTITUENT POLARIZABILITY PARAMETERS FROM ABINITIO CALCULATIONS OF POLARIZABILITY POTENTIALS [J].

HEHRE, WJ ;

PAU, CF ;

HEADLEY, AD ;

TAFT, RW ;

TOPSOM, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (07) :1711-1712

[8]

Johnson C.D., 1973, HAMMETT EQUATION

[9] Ion-Dipole Interaction (Polarization Effect) in Compounds of the Group 14 Elements (A Review) [J].

Kuznetsova, O. V. ;

Egorochkin, A. N. ;

Khamaletdinova, N. M. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (12) :2352-2372

[10] Substituent effects in donor-acceptor complexes with D→A coordination bonds (D = N, O, S; A = B, Al, Ga, Sn, Sb) and related systems [J].

Kuznetsova, O. V. ;

Egorochkin, A. N. ;

Novikova, O. V. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2006, 76 (04) :554-562

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