Effect of cation and anion sizes of additive ionic liquid on the crystal structure of poly(vinylidene fluoride) nanofiber

被引：1
作者：
Asai, Hanako [1 ]
Saga, Hiroyuki [1 ]
Saito, Ryuto [1 ]
Nakane, Koji [1 ]
机构：
[1] Univ Fukui, Grad Sch Engn, Frontier Fiber Technol & Sci Course, 3 9 1 Bunkyo, Fukui 9108507, Japan
来源：
RSC ADVANCES | 2023年 / 13卷 / 18期
关键词：
BETA; MEMBRANES;
D O I：
10.1039/d3ra01917a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We investigated the additive ionic liquid (IL) type dependence on the crystal structure of poly(vinylidene fluoride) (PVDF) nanofibers. As additive ILs, we used imidazolium based ILs with different cation and anion sizes. From differential scanning calorimetry (DSC) measurements, we found that there is a proper amount for the additive IL to promote PVDF crystallization, and the proper amount is influenced by the cation size, not by the anion size. In addition, it was found that IL itself inhibited the crystallization, but IL can promote crystallization under the presence of DMF.
引用
收藏
页码：12000 / 12008
页数：9
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