Features of rare earth elements geochemistry in coals of Central Kazakhstan

This research presents the results of a comprehensive study of mineralogical and geochemical features of REE distribution in coals of Central Kazakhstan deposits-Karaganda coal basin and Shubarkol deposit, which have large hard coal reserves and are industrially important for the coal industry of Kazakhstan; the research is based on 205 samples of clayey interlayers and coal seams. It shows basic patterns of distribution and features of concentration for impurity elements, gives an estimate of the impurity elements concentration, including REE, defines conditions and factors of their accumulation, and studies features of their forms in coal and coal-bearing rocks, which allows estimating the mechanisms of their migration and conditions of accumulation. According to the results of geochemical indicators, the article establishes the factors of REE dislocation, reveals the composition of margin rocks that have influenced REE concentration in coal seams, and the presented latest data on mineralogy allowed to establish the ways of their transportation to the paleobasin during the syn- and epigenetic periods of formation of the coal deposits of Central Kazakhstan being researched. It was found that the coals are insignificantly enriched with heavy lanthanides from Ho to Lu. The distribution curves of UCC normalized REE values in the coals are similar and coincide, but they are less than the average value for world coal, and amount to only one-third of the UCC. It was found that the highest concentrations of all REE are characteristic of clayey interlayers and oxidized coals. The La/Yb ratio in this case increases upwards along the section, indicating mainly clastogenic mechanism of REE delivery to the coals. In coal and clay samples, the predominant mineral form of REE is light lanthanide phosphates. Identified particles of REE from minerals and their composition peculiarities suppose autigene nature of their formation. The formation of the bulk of autigene minerals occurred during the maturation of brown coals and their transformation into hard ones.