Electrospun nanoscale bent fibrous membrane with controllable porous structure and hydrophilic modification for high-efficiency oil-water separation, particle/bacterial filtration and antibacterial applications

被引:13
|
作者
Xu, Ruixiang [1 ]
Feng, Jianyong [1 ,2 ,3 ,4 ]
Qian, Jianhua [1 ]
Zhang, Lingxiao [5 ]
Li, Shengquan [5 ]
Yang, Yuan [6 ]
Xi, Xiaoqing [7 ]
机构
[1] Zhejiang Sci Tech Univ, Int Inst Silk, Coll Text Sci & Engn, 928,2nd St, Hangzhou 310018, Peoples R China
[2] Key Lab Intelligent Text & Flexible Interconnect Z, Hangzhou, Peoples R China
[3] Fudan Univ, State Key Lab Mol Engn Polymers, Shanghai, Peoples R China
[4] Univ Cambridge, Cavendish Lab, JJ Thomson Ave, Cambridge CB3 0HE, England
[5] Hangzhou Deefine Filtrat Technol Co Ltd, Res & Dev Ctr Electrospinning Fibers, Hangzhou 311122, Peoples R China
[6] Shijiazhuang Yiling Pharmaceut Co Ltd, 238 Tianshan St, Shijiazhuang 050035, Peoples R China
[7] Key Lab Safety Evaluat Med Devices Zhejiang Prov, Hangzhou, Peoples R China
关键词
Low-viscosity electrospun; Nanofiber membranes; Hydrophilic modification; Water filtration; Antibacterial; PERFORMANCE; FIBERS; IDENTIFICATION; GALLOTANNINS; FABRICATION; NANOFIBERS; FLUX;
D O I
10.1016/j.memsci.2023.121907
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Electrospun nanofiber membranes' pore structure and hydrophilicity are essential for water filtration. Pore size may be efficiently lowered in this work by decreasing the fiber diameter, changing the fiber morphology, and constructing a silicon hybrid hydrophilic coating. The hydrophilic nanofiber membranes have a small pore size (0.72 & mu;m) and an extremely low diameter (73.5 nm). Meanwhile, the synergistic combination of catechol (CA) and tannic acid (TA) with & gamma;-(2, 3-epoxypropyl) propyl trimethoxysilane (KH560) resulted in the formation of a homogenous silicon hybrid hydrophilic coating on the surface of the fiber membrane. The hydrophilic nanofiber membrane has an outstanding hydrophilicity (WCA = 28.3 degrees), excellent oil-in-water emulsion separation efficiency (>99.0%), extremely high particle filtration efficiency (>99.0%), and an LRV value of more than 7.50 for Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). At 6.0 mg/mL, the antibacterial efficiency was 80% against E. coli and 96% against S. aureus. The preparation of such hydrophilic membranes can provide a novel strategy for high-quality design and development that can be applied to various water filtration applications.
引用
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页数:15
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