In situ forming dialdehyde xanthan gum-gelatin Schiff-base hydrogels as potent controlled release fertilizers

Controlled release fertilizer (CRF) hydrogels have blossomed into promising materials in agriculture owing to the sus-tained release of the fertilizer and also as soil conditioner. Apart from the traditional CRF hydrogels; Schiff-base hydrogels have garnered significant thrust that release nitrogen slowly in addition to reducing the environmental pol-lution. Herein, we have fabricated Schiff-base CRF hydrogels composed of dialdehyde xanthan gum (DAXG) and gel-atin. The formation of the hydrogels was accomplished via the simplistic in situ crosslinking reaction between the aldehyde groups of DAXG and the amino groups of gelatin. The hydrogels acquired a compact network upon increasing the DAXG content in the matrix. The phytotoxic assay on different plants indicated the hydrogels to be nontoxic. The hydrogels demonstrated good water-retention behaviour in soil, along with reusability even after 5 cycles. A controlled release profile for urea was evident from the hydrogels wherein macromolecular relaxation played a crucial role in the release mechanism. Growth assays on Abelmoschus esculentus (Okra) plant presented an intuitive evaluation on the growth and water-holding capacity of the CRF hydrogel. The present work demonstrated a facile preparation of CRF hydrogels to enhance the utilization of urea and retain soil humidity as fertilizer carriers.