Bulklike Vibrational Coupling of Surface Water Revealed by Sum-Frequency Generation Spectroscopy

被引：6

作者：

Chiang, Kuo-Yang ^{[1
]}

Yu, Xiaoqing ^{[1
]}

Yu, Chun-Chieh ^{[1
]}

Seki, Takakazu ^{[1
]}

Sun, Shumei ^{[2
,3
]}

Bonn, Mischa ^{[1
]}

Nagata, Yuki ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany

[2] Beijing Normal Univ, Dept Phys, Beijing 100875, Peoples R China

[3] Beijing Normal Univ, Appl Opt Beijing Area Major Lab, Beijing 100875, Peoples R China

来源：

PHYSICAL REVIEW LETTERS | 2023年 / 131卷 / 25期

基金：

欧洲研究理事会;

关键词：

O-H GROUPS; AIR/WATER INTERFACE; ISOTOPIC DILUTION; LIQUID WATER; ENERGY; EVAPORATION; SPECTRA;

D O I：

10.1103/PhysRevLett.131.256202

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Vibrational coupling between interfacial water molecules is important for energy dissipation after onwater chemistry, yet intensely debated. Here, we quantify the interfacial vibrational coupling strength through the linewidth of surface-specific vibrational spectra of the water's O-H (O- D) stretch region for neat H2O/D2O and their isotopic mixtures. The local-field-effect-corrected experimental SFG spectra reveal that the vibrational coupling between hydrogen-bonded interfacial water O-H groups is comparable to that in bulk water, despite the effective density reduction at the interface.

引用

页数：7

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