Study of H2O2/Cu2+ Catalyzed Oxidation Process of Maltodextrin

被引：1

作者：

Dai, Hao ^{[1
]}

Yao, Wengao ^{[2
]}

Zhou, Xiaohu ^{[2
]}

Tang, Zhuo ^{[2
]}

Zhou, Qiang ^{[2
]}

Li, Xi ^{[2
]}

机构：

[1] Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China

[2] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Wuhan 430070, Peoples R China

来源：

CATALYSTS | 2023年 / 13卷 / 04期

关键词：

maltodextrin; hydrogen peroxide; cupric ion; carboxyl group; FERRIC CARBOXYMALTOSE; OXIDIZED STARCHES; METAL-IONS; HYPOCHLORITE;

D O I：

10.3390/catal13040733

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, oxidized maltodextrins with a high concentration of carboxyl groups were produced using CuSO4 as a catalyst and H2O2 as an eco-friendly oxidant. Infrared spectroscopy, proton-nuclear magnetic resonance spectroscopy, and thermogravimetric analysis were utilized to examine the structure and properties of oxidized maltodextrins. The reaction conditions were optimized in terms of oxidant content, catalyst content, temperature, pH, and reaction time. The prepared oxidized maltodextrin had a carboxyl group content of 105% under the conditions of 200% molar H2O2, 1% molar catalyst, 55 degrees C, initial pH = 9.7, and 2 h reaction time. In comparison to the commonly used sodium hypochlorite oxidation process, the carboxyl group content was increased by 58%.

引用

页数：9