A copper(I) coordination polymer with 3-cyanopyridine ligands

被引：0
|
作者：
Deng, Cui-Er [1 ]
Zhu, Yu-Shu [1 ]
Zhang, Xue-Chun [1 ]
Tao, Yan-Lin [1 ]
Liu, Xi [1 ]
机构：
[1] Chongqing Normal Univ, Coll Chem, Chongqing Key Lab Green Synth & Applicat, Chongqing 401331, Peoples R China
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2023年 / 78卷 / 7-8期
关键词：
coordination polymer; copper(I) complex; crystal structure; cyanopyridine; photoluminescence; STRUCTURAL DIVERSITY; COMPLEXES; PHOTOLUMINESCENCE; HYDROGEN;
D O I：
10.1515/znb-2023-0004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A coordination polymer Cu(3-CP)(3)(NO3) (1) was synthesized from copper(II) sulfate and 3-cyanopyridine (3-CP) with in-situ reduction by hydroxylamine sulfate via the solvent evaporation method at room temperature, and structurally characterized by single-crystal X-ray diffraction and elemental analysis. Complex 1 exhibits a structure formed by cationic [Cu(3-CP)(3)]( n )(n+) chains and NO3- anions with abundant supramolecular interactions. Solid-state photoluminescence experiments show that complex 1 exhibits a relatively strong blue-green emission, and its possible emission mechanism was investigated in detail based on theoretical calculations.
引用
收藏
页码：435 / 439
页数：5
相关论文
共 50 条
  • [11] 3-CYANOPYRIDINE AND 4-CYANOPYRIDINE COMPLEXES OF PENTACYANOFERRATE(II) AND PENTACYANOCOBALTATE(III)
    MORENO, NGDV
    KATZ, NE
    OLABE, JA
    AYMONINO, PJ
    INORGANICA CHIMICA ACTA, 1979, 35 (02) : 183 - 188
  • [12] Hydrolysis kinetics of 2-cyanopyridine, 3-cyanopyridine, and 4-cyanopyridine in high-temperature water
    Fu, Jie
    Ren, Haoming
    Shi, Chaojun
    Lu, Xiuyang
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2012, 44 (09) : 641 - 648
  • [13] STUDIES ON THE REACTION OF 3-CYANOPYRIDINE WITH GRIGNARD-REAGENTS
    GAO, FL
    JIAO, KF
    DING, ZK
    SONG, HQ
    ACTA CHIMICA SINICA, 1987, 45 (09) : 922 - 925
  • [14] Synthesis, crystal structures, thermal and magnetic properties of Mn(NCS)2 coordination compounds with 3-cyanopyridine
    Krebs, Christoph
    Foltyn, Magdalena
    Jess, Inke
    Mangelsen, Sebastian
    Rams, Michal
    Nather, Christian
    INORGANICA CHIMICA ACTA, 2023, 554
  • [15] Bioconversion of 3-cyanopyridine to Nicotinic Acid by a Thermotable Nitrilase
    Nigam, V. K.
    Agarwal, A.
    Sharma, M.
    Ghosh, P.
    Choudhury, B.
    RESEARCH JOURNAL OF BIOTECHNOLOGY, 2009, 4 (01): : 32 - 36
  • [16] Reproductive and developmental toxicity screening test of 3-cyanopyridine in rats
    Takahashi, Mika
    Yabe, Kaoru
    Kato, Hina
    Kawamura, Tomoko
    Matsumoto, Mariko
    Hirata-Koizumi, Mutsuko
    Ono, Atsushi
    Hirose, Akihiko
    REPRODUCTIVE TOXICOLOGY, 2013, 35 : 7 - 16
  • [17] Vertellus to Expand 3-Cyanopyridine and VB3 Production in China
    China Chemical Reporter, 2010, 21 (12) : 8 - 8
  • [18] Adducts of nickel(II) acetylacetonate chelating with heterocyclic bases: 3-cyanopyridine and 4-cyanopyridine
    Zukerman-Schpector, J
    Trindade, AC
    Dunstan, PO
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 (07): : 763 - 765
  • [19] INTRAMOLECULAR ELECTRON-TRANSFER FROM PENTACYANOFERRATE(II) TO PENTAAMMINECOBALT(III) - LINKAGE ISOMERS OF 3-CYANOPYRIDINE AND 4-CYANOPYRIDINE AS BRIDGING LIGANDS
    SZECSY, AP
    HAIM, A
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (11) : 3063 - 3069
  • [20] HYDRATION OF 3-CYANOPYRIDINE TO NICOTINAMIDE BY CRUDE EXTRACT NITRILE HYDRATASE
    EYAL, J
    CHARLES, M
    JOURNAL OF INDUSTRIAL MICROBIOLOGY, 1990, 6 (03): : 185 - 190
12345