Semi-heterogeneous g-C3N4/NaI dual catalytic C-C bond formation under visible light

被引：117

作者：

Song, Hai-Yang ^{[1
]}

Jiang, Jun ^{[1
]}

Wu, Chao ^{[1
]}

Hou, Jia-Chen ^{[1
]}

Lu, Yu-Han ^{[1
]}

Wang, Ke-Li ^{[1
]}

Yang, Tian-Bao ^{[2
]}

He, Wei-Min ^{[1
]}

机构：

[1] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China

[2] Nanjing Forestry Univ, Natl Engn Res Ctr Low Carbon Proc & Utilizat Fores, Nanjing 210037, Peoples R China

来源：

GREEN CHEMISTRY | 2023年 / 25卷 / 08期

关键词：

GRAPHITIC CARBON NITRIDE; CROSS-COUPLING REACTIONS; PHOTOCATALYST; ARYLATION; QUINOXALIN(ON)ES; ALDEHYDES;

D O I：

10.1039/d2gc04843d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The semi-heterogeneous g-C3N4/NaI dual catalytic system-driven C-C bond formation between quinoxalin-2(1H)-ones and arylhydrazines under blue light irradiation has been reported for the first time. The photo-generated hole acted as a traceless oxidant to turn over the iodide salt redox catalyst cycle and the photo-generated electron served as a clean reductant to promote the bond formation process. A wide range of 3-arylquinoxaline-2 (1H)-ones were obtained in high yields with excellent functional group tolerance.

引用

页码：3292 / 3296

页数：5

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