Rare earths;
double perovskite oxides;
magnetic cooling;
magnetocaloric effect;
magnetic properties;
RE;
PERFORMANCES;
GD;
HO;
ER;
ACHIEVEMENT;
DY;
D O I:
10.1007/s11664-024-10993-2
中图分类号:
TM [电工技术];
TN [电子技术、通信技术];
学科分类号:
0808 ;
0809 ;
摘要:
In this work, we fabricated a polycrystalline Tb2FeCrO6 double perovskite (DP) oxide by a solid-state reaction method and determined its structural, magnetic, and magnetocaloric (MC) properties. The Tb2FeCrO6 DP oxide was found to crystallize in a DP-type structure with the Pbnm space group and to undergo a paramagnetic-to-antiferromagnetic transition at a temperature of similar to 8.5 K. A large low-temperature MC effect was observed in the Tb2FeCrO6 DP oxide. The MC parameters in terms of maximum magnetic entropy changes, temperature-averaged entropy change (5 K), and relative cooling power for Tb2FeCrO6 DP oxide under a magnetic field change of 0-7 T were 12.9 J/kg K, 12.7 J/kg K, and 341.4 J/kg, respectively. These parameters were consistent with similarly high levels in recently updated MC materials, making the material a suitable candidate for low-temperature magnetic cooling applications.