Overcoming strength-toughness trade-off in a eutectic high entropy alloy by optimizing chemical and microstructural heterogeneities

被引:16
作者
Chen, Zhaoqi [1 ]
Zhu, Wenqing [1 ]
Wang, Hang [1 ]
He, Quanfeng [1 ,2 ]
Fang, Qihong [3 ]
Liu, Xiaodi [4 ]
Li, Jia [3 ]
Yang, Yong [1 ,5 ]
机构
[1] City Univ Hong Kong, Dept Mech Engn, Kowloon Tong, Kowloon, Hong Kong 999077, Peoples R China
[2] Shanghai Jiao Tong Univ, Inst Mat Modificat & Modelling, Sch Mat Sci & Engn, Shanghai 200240, Peoples R China
[3] Hunan Univ, Coll Mech & Vehicle Engn, State Key Lab Adv Design & Mfg Vehicle Body, Changsha 410082, Peoples R China
[4] Shenzhen Univ, Coll Mechatron & Control Engn, Shenzhen 518060, Peoples R China
[5] City Univ Hong Kong, Dept Mat Sci & Engn, Kowloon Tong, Kowloon, Hong Kong 999077, Peoples R China
关键词
PHASE-FIELD MODELS; MECHANICAL-PROPERTIES; CASTING DEFECTS; HIGH-DUCTILITY; BEHAVIOR; PLASTICITY;
D O I
10.1038/s43246-024-00450-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The well-known strength-toughness trade-off has long been an obstacle in the pursuit of advanced structural alloys. Here, we develop a eutectic high entropy alloy that effectively overcomes this limitation. Our alloy is composed of face-centered cubic and body-centered cubic crystalline phases, and demonstrates attractive mechanical properties by harnessing microstructural hybridization and a strain-induced phase transition between phases. Unlike conventional eutectic alloys, the compositionally complexity of our alloy allows control of its microstructural and chemical heterogeneities across multiple length scales, ranging from atomic- and nano-scales to meso-scales. Optimizing these microstructural and chemical heterogeneities within our alloy enables high strength and ductility because of enhanced fracture resistance, outperforming alternative high and medium entropy alloys with similar compositions and microstructures. Overcoming the strength-toughness trade-off is a key goal of alloy engineering. Here, a two-phase eutectic high entropy alloy is reported that harnesses microstructural and chemical heterogeneity to achieve high toughness and ductility.
引用
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页数:11
相关论文
共 74 条
[1]  
A C., 1885, Annales des Ponts et Chaussees, V9
[2]  
Alnaes M., 2015, Archive of numerical software 3.100, V3, DOI [10.11588/ans.2015.100.20553, DOI 10.11588/ANS.2015.100.20553]
[3]   Eutectic/eutectoid multi-principle component alloys: A review [J].
Baker, Ian ;
Wu, Margaret ;
Wang, Zhangwei .
MATERIALS CHARACTERIZATION, 2019, 147 :545-557
[4]   Tensile instability in face-centred cubic materials [J].
Basinski, ZS ;
Szczerba, MS ;
Embury, JD .
PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1997, 76 (04) :743-752
[5]   Microstructures and mechanical properties of a directionally solidified NiAl-Mo eutectic alloy [J].
Bei, H ;
George, EP .
ACTA MATERIALIA, 2005, 53 (01) :69-77
[6]   Ncorr: Open-Source 2D Digital Image Correlation Matlab Software [J].
Blaber, J. ;
Adair, B. ;
Antoniou, A. .
EXPERIMENTAL MECHANICS, 2015, 55 (06) :1105-1122
[7]   Transforming solid-state precipitates via excess vacancies [J].
Bourgeois, Laure ;
Zhang, Yong ;
Zhang, Zezhong ;
Chen, Yiqiang ;
Medhekar, Nikhil, V .
NATURE COMMUNICATIONS, 2020, 11 (01)
[8]   STRENGTHS AND FAILURE MECHANISMS OF A CO-15CR-13TAC DIRECTIONALLY SOLIDIFIED EUTECTIC ALLOY [J].
BUCHANAN, ER ;
TARSHIS, LA .
METALLURGICAL TRANSACTIONS, 1974, 5 (06) :1413-1422
[9]   FREE ENERGY OF A NONUNIFORM SYSTEM .1. INTERFACIAL FREE ENERGY [J].
CAHN, JW ;
HILLIARD, JE .
JOURNAL OF CHEMICAL PHYSICS, 1958, 28 (02) :258-267
[10]   Microstructural development in equiatomic multicomponent alloys [J].
Cantor, B ;
Chang, ITH ;
Knight, P ;
Vincent, AJB .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 375 :213-218