Rapid and stable hydrogen detection based on Pd-modified WO3 nanosheets

被引:2
作者
Lv, Jianxin [1 ]
Zhang, Linghui [1 ]
Si, Lianxi [3 ]
Li, Hui [1 ,2 ]
Zhao, Wenbo [1 ]
An, Fei [4 ]
Feng, Xia [1 ]
Hu, Shi [1 ,2 ]
机构
[1] Tianjin Univ, Sch Sci, Dept Chem, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300072, Peoples R China
[2] Inst Energy, Hefei Comprehens Natl Sci Ctr, Hefei 230000, Anhui, Peoples R China
[3] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
[4] SINOPEC Res Inst Safety Engn Co Ltd, State Key Lab Safety & Control Chem, Songling Rd 339, Qingdao 266000, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
MESOPOROUS WO3; THIN-FILMS; NANOPARTICLES; SEMICONDUCTOR; SENSITIZATION; PERFORMANCE; DEPOSITION; CATALYSTS; ANGLE;
D O I
10.1039/d3dt00338h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Materials with accurate and durable gas detection are essential for gas sensors. We developed a facile and effective method to deposit Pd onto WO3 nanosheets and used the samples for hydrogen gas sensing. The combination of the 2D ultrathin nanostructure of WO3 and the spillover effect of Pd enables a detection concentration down to 20 ppm of hydrogen and high selectivity against other gases including methane, butane, acetone, isopropanol, etc. Moreover, the durability of the sensing materials was testified through 50 cycles of exposure to 200 ppm of hydrogen. These outstanding performances are mainly attributed to a homogeneous and tenacious decoration of Pd on the surface of WO3 nanosheets, providing an attractive choice for practical applications.
引用
收藏
页码:4200 / 4206
页数:7
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