Adsorption of methyl red from aqueous solution using Bali cow bones (Bos java']javanicus domesticus) hydrochar powder

被引:116
作者
Neolaka, Yantus A. B. [1 ]
Lawa, Yosep [1 ]
Naat, Johnson [1 ]
Lalang, Arvinda C. [1 ]
Widyaningrum, Bernadeta Ayu [2 ]
Ngasu, Gilbertus F. [3 ]
Niga, Krisanti A. [3 ]
Darmokoesoemo, Handoko [4 ]
Iqbal, Munawar [5 ]
Kusuma, Heri Septya [6 ]
机构
[1] Univ Nusa Cendana, Fac Educ & Teachers Training, Dept Chem Educ, Kupang 85001, Nusa Tenggara T, Indonesia
[2] Natl Res & Innovat Agcy BRIN, Reseach Ctr Biomass & Bioprod, Jalan Raya Bogor Km 46, Cibinong 16911, West Java, Indonesia
[3] Univ Nusa Cendana, Fac Educ & Teachers Training, Dept Chem Educ, Analyt Chem Res Grp, Kupang 85001, Nusa Tenggara T, Indonesia
[4] Airlangga Univ, Fac Sci & Technol, Dept Chem, Surabaya 60115, Indonesia
[5] Univ Educ, Dept Chem, Div Sci & Technol, Lahore, Pakistan
[6] Univ Pembangunan Nas Vet Yogyakarta, Fac Ind Technol, Dept Chem Engn, Yogyakarta, Indonesia
关键词
Adsorption; Bones; Hydrochar; Methyl red; Wastewater; KINETICS; CR(VI); SEQUESTRATION; EQUILIBRIUM; ISOTHERMS; PYROLYSIS; ADSORBENT; REMOVAL; DYES; FE;
D O I
10.1016/j.rineng.2022.100824
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Beef consumption produces a lot of bone waste. Here, We prepared Bali cow bones-based hydrochar material (BCBHP) using the hydrothermal carbonization (HTC) method. The resulting BCBHP material was then char-acterized using XRD, FTIR, FESEM-EDX, and BET-BJH. Next, the BCBHP was applied to adsorb methyl red in water samples. Adsorption was carried out using a bath system. Adsorption of methyl red persisted optimum for 30 min at pH 6 at 303.15 K, with a capacity of 7.2 mg g-1. The Zeta potential of BCBHP is-24.4 mV suggesting a higher electrostatic attraction between methyl red dye and BCBHP surface. Methyl red adsorption fitted with pseudo-second-order kinetics model. Adsorption of Methyl red dye on BCBHP follows the Freundlich isotherm model and is well described by a heterolayer adsorption pattern. Thermodynamic studies show that adsorption processes are spontaneous, exothermic, and chemisorption reactions. Moreover, BCBHP has an excellent reus-ability performance that could be used as a promising adsorbent for dye removal in wastewater treatment.
引用
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页数:10
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