RATIONAL DESIGN AND CONVENIENT SYNTHESIS OF TWO NOVEL FERROCENE-BASED SULFONYL DIAMINE PRECURSORS

被引：0

作者：

Gallardo, Miguel ^{[1
]}

Arancibia, Rodrigo ^{[1
]}

Roussel, Pascal ^{[2
]}

Henry, Natacha ^{[2
]}

机构：

[1] Univ Concepcion, Fac Ciencias Quim, Concepcion, Chile

[2] Univ Lille, Unite Catalyse & Chim Solide, Lille, France

来源：

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2023年 / 68卷 / 01期

关键词：

Cyclic voltammetry; ferrocene; organometallic; sulfonamide; X-ray; ANTI-MYCOBACTERIUM-TUBERCULOSIS; ANHYDRASE INHIBITORS SYNTHESIS; CRYSTAL-STRUCTURES; DERIVATIVES; SULFONAMIDES; CYRHETRENYL; ANTICANCER; COMPLEXES; ACID;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the search of new organometallic precursors, this contribution describes a convenient synthesis to obtain new ferrocene-based sulfonyl diamine derivatives. The [(?(5)-C5H4SO2NH-CH2-CH2-NH2)Fe(?(5)-C5H5)] (1) and [(?(5)-C5H4SO2NH-C6H4-NH2)Fe(?(5)-C5H5)] (2) compounds were prepared by the reaction between (?(5)- C5H4SO2Cl)Fe(?(5)-C5H5) and the respective diamine precursor: ethylenediamine (1) orp-phenylenediamine (2) in good yields (86% for 1; 70% for 2). Both compounds were characterized by conventional spectroscopic techniques (infrared spectroscopy, nuclear magnetic resonance spectroscopy, mass spectrometry and elemental analysis) and cyclic voltammetry. In addition, the molecular structure of 1 was determined by single-crystal X-ray diffraction.

引用

页码：5741 / 5744

页数：4

共 51 条

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