Palladium-Catalyzed Suzuki-Miyaura cross-coupling reactions employing hydrazone-thioether ligands in aqueous media under IR-irradiation

被引：0
作者：
Reyes-Deloso, Alberto [1 ]
Penieres-Carrillo, Jose Guillermo [1 ]
Rios-Guerra, Hulme [1 ]
Lagunas-Rivera, Selene [2 ]
Galvan-Garcia, Emir A. [3 ]
Gomez-Balderas, Rodolfo [3 ]
Ortega-Jimenez, Fernando [1 ]
机构：
[1] UNAM, Fac Estudios Super Cuautitlan, Dept Ciencias Quim, Ave 1ro Mayo S-N, Cuautitlan 54740, Estado De Mexic, Mexico
[2] Univ Guanajuato, Dept Quim, Catedra CONACyT, Noria Alta S-N, Guanajuato 36050, Guanajuato, Mexico
[3] Univ Nacl Autonoma Mexico, Fac Estudios Super Cuautitlan, Unidad Invest Multidisciplinaria, Lab Fisicoquim Analit, Cuautitlan 54714, Estado De Mexic, Mexico
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2023年 / 1294卷
关键词：
Hydrazone-thioether ligands; Palladium-catalyzed; Cross-coupling reaction; Aqueous media; IR-irradition; SULFENYLATED CARBONYL-COMPOUNDS; SULFUR-CONTAINING PALLADACYCLES; C-C; MIZOROKI-HECK; SOLVENT-FREE; PROPARGYLIC ALCOHOLS; ARYL CHLORIDES; PD(II) COMPLEX; EFFICIENT; WATER;
D O I：
10.1016/j.molstruc.2023.136562
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An in situ catalytic system was generated based on hydrazone-thioether ligands and Pd(OAc)2. It provided excellent catalytic activity in the Suzuki-Miyaura cross-coupling reactions between aryl halides and arylboronic acids in aqueous medium and under IR irradiation. The resulting coupled products were obtained in short re-action times, with low catalyst loads and in good to excellent yields. Density functional theory based compu-tations were applied to characterize the probable structure of the dimeric complex formed between the hydrazone and Pd(OAc)2, afterwards structure was confirmed by experimental analysis of IR and ESI mass spectrometry.
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页数：9
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