Comparative Analysis of the Results of the Online Determination of Hydrogen Sulfide and the Results Obtained by Photometry and Chromatography-Mass Spectrometry

被引：0

作者：

Valieva, E. F. ^{[1
]}

Khatmullina, R. M. ^{[2
]}

Safarova, V. I. ^{[2
]}

Goncharova, I. P. ^{[2
]}

机构：

[1] Bashkir State Univ, Fac Chem, Ufa 450074, Bashkortostan, Russia

[2] State Budgetary Inst Republ Bashkortostan, Dept State Analyt Control, Ufa 450104, Bashkortostan, Russia

来源：

JOURNAL OF ANALYTICAL CHEMISTRY | 2023年 / 78卷 / 01期

关键词：

environmental control; hydrogen sulfide; automated control systems; gas analyzer; chromatography-mass spectrometry; photometry; SEMIVOLATILE ORGANIC-COMPOUNDS; SAMPLING METHODS; VOLATILE; AIR; DETECTOR; LEVEL;

D O I：

10.1134/S1061934823010124

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The results of the determination of sulfur-containing compounds in atmospheric air polluted by products of the depressurization of a product pipeline with gas condensate are presented. Hydrogen sulfide was determined online using mobile automatic control stations and by photometry in a stationary laboratory. Organic sulfur-containing compounds (mercaptans, sulfides, disulfides) were identified by chromatography-mass spectrometry. It was found that the results of the analysis obtained in the automatic mode reflect the total content of hydrogen sulfide and some organosulfur compounds.

引用

页码：91 / 95

页数：5

共 15 条

[1] Akopyan A.V., 2015, CAND SCI CHEM
[2] [Anonymous], 1991, RD GUIDELINES 520418
[3] [Anonymous], 2014, RD GUIDELINES 520479
[4] Drugov Yu.S., 1999, GAZOKHROMATOGRAFICHE
[5] From a survey on accidents in the downstream oil industry to the development of a detailed near-miss reporting system
Fabiano, B.
Curro, F.
[J]. PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, 2012, 90 (05) : 357 - 367
[6] Goryacheva M.Yu., 2018, GASTRIC CANCER, V2, P653
[7] Methods of determination of organic compounds in air
Krylov, V. A.
Mosyagin, P. V.
Mikhirev, D. A.
Eremin, S. A.
Krylov, A. V.
[J]. RUSSIAN CHEMICAL REVIEWS, 2010, 79 (06) : 531 - 542
[8] Evaluation of a commercial pulsed fluorescence detector for the measurement of low-level SO2 concentrations during the gas-phase sulfur intercomparison experiment
Luke, WT
[J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1997, 102 (D13) : 16255 - 16265
[9] Maistrenko V.N., 1996, EKOLOGO ANALITICHESK
[10] AMBIENT AND SOURCE SO2 DETECTOR BASED ON A FLUORESCENCE METHOD
OKABE, H
SPLITSTONE, PL
BALL, JJ
[J]. JOURNAL OF THE AIR POLLUTION CONTROL ASSOCIATION, 1973, 23 (06): : 514 - 516

← 1 2 →