Octafluoro-Substituted Phthalocyanines of Zinc, Cobalt, and Vanadyl: Single Crystal Structure, Spectral Study and Oriented Thin Films

被引:9
作者
Sukhikh, Aleksandr [1 ]
Klyamer, Darya [1 ]
Bonegardt, Dmitry [1 ]
Basova, Tamara [1 ]
机构
[1] SB RAS, Nikolaev Inst Inorgan Chem, 3 Lavrentiev Pr, Novosibirsk 630090, Russia
基金
俄罗斯科学基金会;
关键词
metal phthalocyanines; fluorine substituents; single crystal structure; thin films; X-ray diffraction; conductivity; MOLECULAR SEMICONDUCTOR; ELECTROCHEMICAL SENSORS; VAPOR-PRESSURE; FLUOROSUBSTITUTION;
D O I
10.3390/ijms24032034
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
In this work, octafluoro-substituted phthalocyanines of zinc, vanadyl, and cobalt (MPcF8, M = Zn(II), Co(II), VO) were synthesized and studied. The structures of single crystals of the obtained phthalocyanines were determined. To visualize and compare intermolecular contacts in MPcF8, an analysis of Hirshfeld surfaces (HS) was performed. MPcF8 nanoscale thickness films were deposited by organic molecular beam deposition technique and their structure and orientation were studied using X-ray diffraction. Comparison of X-ray diffraction patterns of thin films with the calculated diffractograms showed that all three films consisted of a single crystal phase, which corresponded to a phase of single crystals. Only one strong diffraction peak corresponding to the plane (001) was observed on the diffraction pattern of each film, which indicated a strong preferred orientation with the vast majority of crystallites oriented with a (001) crystallographic plane parallel to the substrate surface. The effect of the central metals on the electronic absorption and vibrational spectra of the studied phthalocyanines as well as on the electrical conductivity of their films is also discussed.
引用
收藏
页数:16
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