Recent Advances in Palladium-Catalyzed Asymmetric Heck/Tsuji-Trost Reactions of 1,n-Dienes

被引：2
|
作者：
Zhao, Guofeng [1 ,2 ]
Li, Wenbo [2 ]
Zhang, Junliang [2 ,3 ]
机构：
[1] Henan Univ Sci & Technol, Sch Chem & Chem Engn, Luoyang 471023, Peoples R China
[2] East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, State Key Lab Petr Mol & Proc Engn, 3663 N Zhongshan Rd, Shanghai 200062, Peoples R China
[3] Fudan Univ, Dept Chem, 2005 Songhu Rd, Shanghai 200438, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2024年 / 30卷 / 26期
基金：
国家重点研发计划; 中国国家自然科学基金;
关键词：
Palladium; Heck/Tsuji-Trost; Difunctionalization; Asymmetric catalysis; 1; n-Dienes; FUNCTIONALLY-SUBSTITUTED ARYL; HECK-TYPE REACTIONS; NITROGEN-HETEROCYCLES; NONCONJUGATED DIENES; COUPLING CYCLIZATION; CONJUGATED DIENES; CASCADE REACTIONS; CHIRAL LIGANDS; MIZOROKI-HECK; DIFUNCTIONALIZATION;
D O I：
10.1002/chem.202400076
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transition-metal catalyzed tandem asymmetric reactions were powerful tools to access various chiral compounds. Many strategies have been developed for the coupling of 1,n-dienes with aryl halides via a tandem Heck/Tsuji-Trost process. However, the control of regio- and stereo-chemistry remains a challenging task. This minireview details the recent advances in the field of asymmetric Heck/Tsuji-Trost reactions catalyzed by palladium complex, which have opened new opportunities and expanded our understanding in this area of research in recent years. The Pd-catalyzed asymmetric tandem Heck/Tsuji-Trost reaction provided a powerful method for the preparation of various chiral compounds containing an allylic moiety. Chiral palladium/phosphine complex efficiently promoted a wide range of difunctionalization of 1,n-dienes (n=2-4) for constructing C-C and C-X (X=C, O, N) bond simultaneously. This review summarizes the recent advances in this field and highlights the significant achievements. image
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页数：14
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