Synthesis, crystal structure and Hirshfeld surface analysis of 3-(4-fluorophenyl)-2-formyl-7-methylimidazo[1,2-a]pyridin-1-ium chloride monohydrate

被引：0

作者：

Guseinov, Firudin I. ^{[1
,2
]}

Ovsyannikov, Viacheslav O. ^{[2
,3
]}

Sokolovskiy, Pavel V. ^{[2
]}

Sebyakin, Yurii L. ^{[3
]}

Samigullina, Aida I. ^{[2
]}

Akkurt, Mehmet ^{[4
]}

Celikesi, Sevim Turktekin ^{[5
]}

Bhattarai, Ajaya ^{[6
]}

机构：

[1] Kosygin State Univ Russia, Moscow 117997, Russia

[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

[3] Russian Technol Univ, Lomonosov Inst Fine Chem Technol, MIREA, Moscow 119571, Russia

[4] Erciyes Univ, Dept Phys, Fac Sci, TR-38039 Kayseri, Turkiye

[5] Erciyes Univ, Dept Phys, Fac Sci, TR-38039 Kayseri, Turkiye

[6] MMAMC Tribhuvan Univ, Dept Chem, Biratnagar, Nepal

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷

关键词：

crystal structure; imidazo[1,2-a]pyridin-1-ium; hydrogen bonds; pi-pi interactions; Hirshfeld surface analysis; ARYLHYDRAZONE; COORDINATION; COMPLEXES; ACID;

D O I：

10.1107/S2056989023007272

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title salt, C15H12FN2O+center dot Cl-center dot H2O, the imidazo[1,2-a]pyridin-1-ium ring system of the cation is almostly planar [maximum deviaition = -0.047 (2) angstrom for the ring C atom with the attached arene ring] and forms a dihedral angle of 61.81 (6)degrees with the plane of the fluorophenyl ring. In the crystal, water molecules form an R-2(4) (8) motif parallel to the (100) plane by bonding with the chloride ions via O-H...Cl hydrogen bonds. The cations are connected along the b axis via N-H center dot center dot center dot O hydrogen bonds involving the O atoms of water molecules, and C-H center dot center dot center dot O, C-H center dot center dot center dot Cl and pi-pi interactions [centroid-to-centroid distance = 3.6195 (8) angstrom] form layers parallel to the (100) plane. Furthermore, these layers are connected via pi-pi interactions [centroid-to-centroid distance = 3.8051 (9) angstrom] that further consolidate the crystal structure.

引用

页码：899 / +

页数：11

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