Synthesis and Properties of Metal Complexes with Halogen-Substituted Octaphenyltetraazaporphyrins

被引：2

作者：

Chizhova, N. V. ^{[1
]}

Likhonina, A. E. ^{[1
]}

Mamardashvili, N. Z. ^{[1
]}

机构：

[1] Russian Acad Sci, GA Krestov Inst Solut Chem, Ivanovo 153040, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / 06期

关键词：

complexes with octa-(4-halophenyl)tetraazaporphyrins; cyclomerization reactions; metal exchange reactions; photochemical stability; PORPHYRAZINE;

D O I：

10.1134/S1070363223060154

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By reactions of di(4-halophenyl)maleindinitriles with magnesium and zinc(II) acetates in boiling ethylene glycol, Mg(II)-octa-(4-chlorophenyl)tetraazaporphyrin, Mg(II)-octa-(4-fluorophenyl)-tetraazaporphyrin, Zn(II)-octa-(4-chlorophenyl)tetraazaporphyrin, and Zn(II)-octa-(4-fluorophenyl)tetraazaporphyrins were synthesized. The cyclomerization of diphenylmaleinitrile with zinc acetate in ethylene glycol resulted in Zn(II)-Octaphenyltetraazaporphyrin. The corresponding Cu(II) and Mn(III)-octaphenyltetraazaporphyrins were synthesized in dimethylformamide using the metal exchange reaction of halogen-substituted magnesium complexes with copper(II) and manganese(II) chlorides. The obtained compounds were identified by electron absorption, IR, and H-1 NMR spectroscopy, and mass spectrometry. The photochemical stability of the synthesized complexes was studied.

引用

页码：1433 / 1439

页数：7

共 19 条

[1] MANGANESE PORPHYRIN COMPLEXES [J].

BOUCHER, LJ .

COORDINATION CHEMISTRY REVIEWS, 1972, 7 (03) :289-&

[2] Water exchange rates of water-soluble manganese(III) porphyrins of therapeutical potential [J].

Budimir, Ana ;

Jozsef Kalmar ;

Istvan Fabian ;

Lente, Gabor ;

Istvan Banyai ;

Batinic-Haberle, Ines ;

Birus, Mladen .

DALTON TRANSACTIONS, 2010, 39 (18) :4405-4410

[3] Photocatalytic properties and electrochemical characteristic of a novel biomimetic oxygenase enzyme photocatalyst iron(II) tetrahydroxymethyl tetra(1,4-dithiin) porphyrazine for the degradation of organic pollutants [J].

Chen, Lianqing ;

Zhang, Zehui ;

Wang, Yajuan ;

Guan, Yayun ;

Deng, Kejian ;

Lv, Kangle ;

Sun, Jie ;

Li, Zhe ;

Li, Mei .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2013, 372 :114-120

[4] Oxidation catalysis by iron and manganese porphyrins within enzyme-like cages [J].

Chino, Marco ;

Leone, Linda ;

Zambrano, Gerardo ;

Pirro, Fabio ;

D'Alonzo, Daniele ;

Firpo, Vincenzo ;

Aref, Diaa ;

Lista, Liliana ;

Maglio, Ornella ;

Nastri, Flavia ;

Lombardi, Angela .

BIOPOLYMERS, 2018, 109 (10)

[5] Synthesis and Spectral and Fluorescent Properties of Metal Complexes of Octakis(4-flurophenyl)tetraazaporphyrins [J].

Chizhova, N. V. ;

Ivanova, Yu. B. ;

Rusanov, A. I. ;

Khrushkova, Yu. V. ;

Mamardashvili, N. Z. .

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 55 (05) :655-661

[6] Phthalocyanines. Part XI. The preparation of octaphenyl diphenylmaleinitrile. [J].

Cook, AH ;

Linstead, RP .

JOURNAL OF THE CHEMICAL SOCIETY, 1937, :929-933

[7] Spectral-Fluorescence Properties of Zn(II)-Octaphenyltetraazaporphyrins [J].

Dmitrieva, Olga A. ;

Chizhova, Natalya, V ;

Rusanov, Alexey, I ;

Koifman, Mikhail O. ;

Mamardashvili, Nugzar Z. .

JOURNAL OF FLUORESCENCE, 2020, 30 (03) :657-664

[8] Oxidation of alkanes and alkenes by iodosylbenzene and hydrogen peroxide catalysed by halogenated manganese porphyrins in homogeneous solution and covalently bound to silica [J].

Doro, FG ;

Smith, JRL ;

Ferreira, AG ;

Assis, MD .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 164 (1-2) :97-108

[9]

Enikolopyan N.S., 1987, PORFIRINY SPEKTROSKO

[10] Potential Aluminium(III)- and Gallium(III)-selective Optical Sensors Based on Porphyrazines [J].

Goslinski, Tomasz ;

Tykarska, Ewa ;

Kryjewski, Michal ;

Osmalek, Tomasz ;

Sobiak, Stanislaw ;

Gdaniec, Maria ;

Dutkiewicz, Zbigniew ;

Mielcarek, Jadwiga .

ANALYTICAL SCIENCES, 2011, 27 (05) :511-515

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