Regulation Dipole Moments of N-Doped Graphene Coordinated with FePc Toward Highly Efficient Microwave Absorption Performance in C Band

被引:22
作者
Zhang, Jinming [1 ]
Chen, Lin [1 ]
Li, Xing [1 ]
Cao, Haijie [1 ]
Chen, Wansong [1 ]
Wang, Xiaoxia [1 ]
机构
[1] Qingdao Univ, Coll Mat Sci & Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China
关键词
charge redistribution; dipole moments; low frequency; microwave absorption; polarization centers; DIELECTRIC-PROPERTIES; NANOPARTICLES; ATTENUATION; NANOSHEETS; BOOST;
D O I
10.1002/smll.202308459
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The development of composites with highly efficient microwave absorption (MA) performance deeply depends on polarization loss, which can be induced by charge redistribution. Considering the fact that polarization centers can be easily obtained in graphene, herein, iron phthalocyanine (FePc) is used as polarization site to coordinate with nitrogen-doped graphene (FePc/N-rGO) to optimize MA performance comprehensively. The factors influencing MA properties focus on the interaction between FePc and N-rGO, and the change of dipole moments. The density functional theory (DFT) results demonstrated that FePc has strong interaction with N defect sites in graphene. The charge loss for FePc and charge accumulation for N-rGO occurred, leading to great increase of dipole moment, and the increased dipole moment can be acted as a descriptor to evaluate the enhanced polarization loss. Due to high charge redistribution capacity of N defect sites and FePc polarization centers, the FePc/N-rGO showed excellent MA properties in C band, and the minimum reflection loss value can reach -49.3 dB at 5.4 GHz with thickness of 3.8 mm. In addition, the fabric loaded with FePc/N-rGO showed good heat dissipation property. This work opens the door to the development of MA performance bound to polarization site with dipole moment. The FePc/N-rGO composites are synthesized by iron phthalocyanine (FePc) coordinating with nitrogen-doped graphene (N-rGO) to optimize the microwave absorption (MA) performance. The charge loss of FePc and charge accumulation of N-rGO produce increased dipole moment, which can be acted as a descriptor to evaluate the enhanced polarization loss. The lab-grown fabric covered with FePc/N-rGO composites has good heat dissipation capacity. image
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页数:11
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