Effect of Fluorosilicone Rubber on Mechanical Properties, Dielectric Breakdown Strength and Hydrophobicity of Methyl Vinyl Silicone Rubber

被引:8
作者
Wang, Zhaoyang [1 ]
Lin, Yankai [2 ]
Li, Zhanxu [1 ]
Yang, Yumeng [1 ]
Lin, Jun [1 ]
He, Shaojian [1 ]
机构
[1] North China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewable, Beijing 102206, Peoples R China
[2] Jiangmen Power Dispatching Ctr Jiangmen Power Grid, Jiangmen 529000, Peoples R China
基金
中国国家自然科学基金;
关键词
silicone rubber; fluorosilicone rubber; mechanical properties; breakdown strength; hydrophobicity; ELECTRICAL BREAKDOWN; PERFORMANCE; COMPOSITES; INSULATION;
D O I
10.3390/polym15163448
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Silicone rubber (SIR) is used in high-voltage insulators because of its insulation, and excel-lent hydrophobicity is very important in harsh outdoor environments. To enhance the hydrophobicity and low-temperature resistance of silicone rubber, methyl vinyl silicone rubber and fluorosilicone rubber (FSIR) blend composites with different ratios were prepared. The samples were characterized and analyzed using scanning electron microscopy, tensile testing, dynamic mechanical analysis and static contact angle testing. The results showed that after blending, SIR and FSIR were well compati-ble. FSIR had higher elastic modulus and reduced the tensile strength to some extent in SIR/FSIR composites. The addition of a small amount of FSIR made its crystallization temperature decrease from -30 to -45 degrees C, meaning that the low-temperature resistance was significantly improved. The breakdown strength of SIR/FSIR composites can still be maintained at a high level when a small amount of FSIR is added. The contact angle of the composites increased from 108.9 to 115.8 degrees with the increase in FSIR content, indicating the enhanced hydrophobicity. When the samples were immersed in water for 96 h, the hydrophobicity migration phenomenon occurred. The static contact angle of the samples with less FSIR content had a weaker decreasing trend, which illustrated that the hydrophobicity was maintained at a high level.
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页数:12
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