Application of imaging techniques for the characterization of lumps behaviour in gas-solid fluidized-bed reactors

Gas-solid fluidized-bed reactors are often used in waste pyrolysis and gasification processes thanks to their excellent mixing properties, which guarantee temperature uniformity. However, this latter property can fail when large objects, such as lumps, are introduced or form in the system. Understanding the motion character-istics and thermal behaviour of lumps in a high temperature fluidized-bed reactor can help determining how the presence of lumps impact reactors' performance. This was the object of this study. In particular, this work aims to assess how process variables and physical properties impact the segregation behaviour, dispersion coefficients and heat transfer coefficients of these lumps during operation. The system used in this work is a down-scaled pseudo-2D fluidized bed operated at ambient temperature and at fluidization velocities ranging between 1 Umf and 10 Umf. Rutile sand with four different mean particle sizes (60 mu m, 100 mu m, 153 mu m and 215 mu m) was used as bed material. Fabricated lumps were introduced in the fluidized bed to reproduce realistic conditions, as when lumps form in a high-temperature fluid bed. The density ratio between the lump and the bed material particle was varied between 0.32 and 0.55 to account for different lump compositions. X-ray digital radiography and infrared thermography were used respectively to track the fabricated lumps and to obtain their temperature time evolution. The lump density was found not to have a significant effect on the lump dispersion coefficients or on the heat transfer coefficient. Optimal values of fluidization velocities that guarantee proper lump mixing and maximum heat transfer coefficient were obtained. This latter increases by up to 10 times if the optimal fluid-ization velocity is selected. An increase in the bed material particle size was found to cause an increase in the dispersion coefficients and a decrease in the heat transfer coefficient. The trend of the heat transfer coefficient as a function of the fluidization velocity was found to vary significantly between different bed material particle sizes. A new correlation for the Nusselt number as a function of the object Reynolds number and of the size ratio between lump and bed material was obtained. This correlation applies to cases where particle convection is the dominant mechanism of heat transfer. The results of this work provide important knowledge to minimize the impact of lumps on fluidized-bed reactors and to optimize their operation.