A practical perspective on the potential of rechargeable Mg batteries

被引:57
作者
Blazquez, J. Alberto [1 ]
Maca, Rudi R. [1 ]
Leonet, Olatz [1 ]
Azaceta, Eneko [1 ]
Mukherjee, Ayan [2 ]
Zhao-Karger, Zhirong [3 ,4 ]
Li, Zhenyou [3 ,4 ]
Kovalevsky, Aleksey [5 ]
Fernandez-Barquin, Ana [1 ]
Mainar, Aroa R. [1 ]
Jankowski, Piotr [6 ]
Rademacher, Laurin [7 ]
Dey, Sunita [8 ]
Dutton, Sian E. [9 ]
Grey, Clare P. [8 ]
Drews, Janina [7 ]
Haecker, Joachim [7 ]
Danner, Timo [3 ,7 ]
Latz, Arnulf [3 ,7 ,10 ]
Sotta, Dane [11 ]
Palacin, M. Rosa [12 ]
Martin, Jean-Frederic
Lastra, Juan Maria Garcia [6 ,11 ]
Fichtner, Maximilian [3 ,4 ]
Kundu, Sumana [13 ,14 ]
Kraytsberg, Alexander [13 ,14 ]
Ein-Eli, Yair [13 ,14 ]
Noked, Malachi [2 ]
Aurbach, Doron [2 ]
机构
[1] CIDETEC, Basque Res & Technol Alliance BRTA, Parque Cientif & Tecnol Gipuzkoa, Paseo Miramon, 196, San Sebastian 20014, Spain
[2] Bar Ilan Univ, Dept Chem, IL-5290002 Ramat Gan, Israel
[3] Helmholtz Inst Ulm HIU Electrochem Energy Storage, D-89081 Ulm, Germany
[4] Karlsruhe Inst Technol KIT, Inst Nanotechnol INT, D-76021 Karlsruhe, Germany
[5] Technion R&D Fdn LTD, Israel Inst Met, Technion City, IL-3200003 H_efa, Israel
[6] Tech Univ Denmark, Dept Energy Convers & Storage, Lyngby, Denmark
[7] German Aerosp Ctr DLR, Inst Engn Thermodynam, Pfaffenwaldring 38-40, D-70569 Stuttgart, Germany
[8] Univ Cambridge, Dept Chem, Cambridge CB2, England
[9] Univ Cambridge, Cavendish Lab, JJ Thomson Ave, Cambridge, Cambridgeshire, England
[10] Ulm Univ, Inst Electrochem, D-89081 Ulm, Germany
[11] CEA LITEN, 17 Rue Martyrs, F-38054 Grenoble 9, France
[12] ICMAB CSIC, Inst Ciencia Mat Barcelona, Campus UAB, Catalonia 08193, Spain
[13] Technion Israel Inst Technol, Dept Mat Sci & Engn, JJ Thomson Ave, IL-3200003 H_aifa, Israel
[14] Technion Israel Inst Technol, Grand Technion Energy Program GTEP, IL-3200003 H_efa, Israel
关键词
HIGH ANODIC STABILITY; MAGNESIUM ALLOYS; LI-ION; ELECTROLYTE-SOLUTIONS; REVERSIBLE MAGNESIUM; CORROSION BEHAVIOR; CATHODE MATERIALS; SULFUR BATTERIES; INTERCALATION; EFFICIENT;
D O I
10.1039/d2ee04121a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Emerging energy storage systems based on abundant and cost-effective materials are key to overcome the global energy and climate crisis of the 21st century. Rechargeable Magnesium Batteries (RMB), based on Earth-abundant magnesium, can provide a cheap and environmentally responsible alternative to the benchmark Li-ion technology, especially for large energy storage applications. Currently, RMB technology is the subject of intense research efforts at laboratory scale. However, these emerging approaches must be placed in a real-world perspective to ensure that they satisfy key technological requirements. In an attempt to bridge the gap between laboratory advancements and industrial development demands, herein, we report the first non-aqueous multilayer RMB pouch cell prototypes and propose a roadmap for a new advanced RMB chemistry. Through this work, we aim to show the great unrealized potential of RMBs.
引用
收藏
页码:1964 / 1981
页数:18
相关论文
共 140 条
[111]   A high energy-density tin anode for rechargeable magnesium-ion batteries [J].
Singh, Nikhilendra ;
Arthur, Timothy S. ;
Ling, Chen ;
Matsui, Masaki ;
Mizuno, Fuminori .
CHEMICAL COMMUNICATIONS, 2013, 49 (02) :149-151
[112]   An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes [J].
Son, Seoung-Bum ;
Gao, Tao ;
Harvey, Steve P. ;
Steirer, K. Xerxes ;
Stokes, Adam ;
Norman, Andrew ;
Wang, Chunsheng ;
Cresce, Arthur ;
Xu, Kang ;
Ban, Chunmei .
NATURE CHEMISTRY, 2018, 10 (05) :532-539
[113]   The Effect of Texture on the Corrosion Behavior of AZ31 Mg Alloy [J].
Song, Guang-Ling .
JOM, 2012, 64 (06) :671-679
[114]   Mapping the Challenges of Magnesium Battery [J].
Song, Jaehee ;
Sahadeo, Emily ;
Noked, Malachi ;
Lee, Sang Bok .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2016, 7 (09) :1736-1749
[115]   A Stable Solid Electrolyte Interphase for Magnesium Metal Anode Evolved from a Bulky Anion Lithium Salt [J].
Tang, Kun ;
Du, Aobing ;
Dong, Shanmu ;
Cui, Zili ;
Liu, Xin ;
Lu, Chenglong ;
Zhao, Jingwen ;
Zhou, Xinhong ;
Cui, Guanglei .
ADVANCED MATERIALS, 2020, 32 (06)
[116]   Study of Electrochemical Phenomena Observed at the Mg Metal/Electrolyte Interface [J].
Tutusaus, Oscar ;
Mohtadi, Rana ;
Singh, Nikhilendra ;
Arthur, Timothy S. ;
Mizuno, Fuminori .
ACS ENERGY LETTERS, 2017, 2 (01) :224-229
[117]   On the strange case of divalent ions intercalation in V2O5 [J].
Verrelli, R. ;
Black, A. P. ;
Pattanathummasid, C. ;
Tchitchekova, D. S. ;
Ponrouch, A. ;
Oro-Sole, J. ;
Frontera, C. ;
Barde, F. ;
Rozier, P. ;
Palacin, M. R. .
JOURNAL OF POWER SOURCES, 2018, 407 :162-172
[118]   On the Study of Ca and Mg Deintercalation from Ternary Tantalum Nitrides [J].
Verrelli, Roberta ;
Philip Black, Ashley ;
Frontera, Carlos ;
Oro-Sole, Judith ;
Elena Arroyo-de Dompablo, Maria ;
Fuertes, Amparo ;
Rosa Palacin, M. .
ACS OMEGA, 2019, 4 (05) :8943-8952
[119]  
VINCENT M, 2021, CHEMSUSCHEM, V506
[120]   Computational Design of Ductile Magnesium Alloy Anodes for Magnesium Batteries [J].
Vincent, Smobin ;
Chang, Jin Hyun ;
Lastra, Juan Maria Garcia .
BATTERIES & SUPERCAPS, 2021, 4 (03) :522-528