Chiral metal-organic frameworks and their composites as stationary phases for liquid chromatography chiral separation: A minireview

被引：28

作者：

Liu, Chunqiang ^{[1
,2
,3
]}

Quan, Kaijun ^{[1
,2
]}

Chen, Jia ^{[1
,2
,3
]}

Shi, Xiaofeng ^{[4
]}

Qiu, Hongdeng ^{[1
,2
,3
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, CAS Key Lab Chem Northwestern Plant Resources, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[4] Gansu Prov Canc Hosp, Inst Mat Med, Lanzhou 730050, Peoples R China

来源：

JOURNAL OF CHROMATOGRAPHY A | 2023年 / 1700卷

关键词：

Chiral metal -organic frameworks; CMOFs composites; Chiral separation; Chiral stationary phase; High-performance liquid chromatography; RECENT PROGRESSES; HPLC SEPARATION; MOF; ENANTIOSEPARATION; CYCLODEXTRIN; SULFOXIDES; RESOLUTION;

D O I：

10.1016/j.chroma.2023.464032

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Chiral metal organic frameworks (CMOFs) are a kind of crystal porous framework material that has attracted increasing attention due to the customizable combination of metal nodes and organic ligands. In particular, the highly ordered crystal structure and rich adjustable chiral structure make it a promising material for developing new chiral separation material systems. In this review, the progress of CMOFs and their different types of composites used as chiral stationary phases (CSPs) in liquid chromatography for enantioseparation are discussed. The characteristics of CMOFs and their composites are summarized, aiming to provide new ideas for the development of CMOFs with better performance and further promote the application of CMOFs materials in enantioselective high-performance liquid chromatography (HPLC). (c) 2023 Elsevier B.V. All rights reserved.

引用

页数：14

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