Solid polymer electrolytes from NaAlg: PVA: effect of ammonium thiocyanate on ionic conductivity

被引：9
作者：
Jansi, R. [1 ,2 ]
Shenbagavalli, S. [1 ,2 ]
Revathy, M. S. [1 ]
Deepalakshmi, S. [2 ,3 ]
机构：
[1] Kalasalingam Acad Res & Educ, Sch Adv Sci, Dept Phys, Virudunagar 626126, Tamil Nadu, India
[2] Kalasalingam Acad Res & Educ, Int Res Ctr, Multifunct Mat Lab, Virudunagar 626126, Tamil Nadu, India
[3] Rajapalayam Rajus Coll, Dept Comp Sci, Rajapalayam, India
来源：
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2023年 / 34卷 / 06期
关键词：
AMINO-ACID PROLINE; ELECTRICAL-PROPERTIES; CHITOSAN; MEMBRANE; PECTIN;
D O I：
10.1007/s10854-023-09825-6
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
PVA: NaAlg with NH4SCN(different wt. %) solid polymer electrolytes(SPE) were prepared by solution casting technique. XRD and FTIR investigations confirmed, polymer's amorphous character and complexation with salt. The Nyquist plot of PVA: NaAlg: NH4SCN(15 wt.%) SPE showed a significant ionic conductivity of 2.27 x 10(-6)S=cm. The relaxation time was1.08 9 10(-4 )s. Linear Sweep Voltammetry studies indicated that prepared SPE have an electro-chemical stability window of 0.7 V. The Cyclic voltammetry investigation exhibited faradaic behavior. Based on these studies, the inclusion of ammonium salt in this reported hybrid polymer blend could be a potential SPE for elec-trochemical devices.
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页数：13
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  • [2] Impedance, FTIR and transport properties of plasticized proton conducting biopolymer electrolyte based on chitosan for electrochemical device application
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    Nofal, Muaffaq M.
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    Hadi, Jihad M.
    Hessien, Mahmoud M.
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  • [8] Structural, thermal and electrical properties of polyvinyl alcohol/poly(vinyl pyrrolidone)-sodium nitrate solid polymer blend electrolyte
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    Saadiah, M. A.
    Yao, Y.
    Nagao, Y.
    Samsudin, A. S.
    [J]. JOURNAL OF POLYMER RESEARCH, 2020, 27 (08)
  • [10] Ghazali NM., 2021, C IOP SER MAT SCI EN, V1092
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