Corrosion mechanism of advanced high strength dual-phase steels by electrochemical noise analysis in chloride solutions

被引:12
作者
Montoya-Rangel, Marvin [1 ]
Garza-Montes-de-Oca, Nelson F. [1 ]
Gaona-Tiburcio, Citlalli [1 ]
Almeraya-Calderon, Facundo [1 ]
机构
[1] Univ Autonoma Nuevo Leon, Fac Ingn Mecan & Elect, Ave Univ S-N,Ciudad Univ, San Nicolas De Los Garza 66455, NL, Mexico
来源
MATERIALS TODAY COMMUNICATIONS | 2023年 / 35卷
关键词
Non -uniform corrosion; Ferrite-martensite dual -phase steel; Ferrite-bainite dual -phase steel; Electrochemical Noise technique; Chloride solutions; LOW-ALLOY STEELS; PITTING CORROSION; STAINLESS-STEEL; CARBON-STEEL; HEAT-TREATMENTS; DISSOLUTION PROCESS; BEHAVIOR; MICROSTRUCTURE; RESISTANCE; NACL;
D O I
10.1016/j.mtcomm.2023.105663
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The corrosion behavior of ferrite-martensite and ferrite-bainite dual-phase steels in NaCl, CaCl2, and MgCl2 solutions was studied by cyclic potentiodynamic polarization (CPP) and electrochemical noise (EN) techniques. The results showed a trend for mixed corrosion due to no passivation by a protective oxide layer. For the ferritemartensite dual-phase steels, the ferrite phase was preferentially corroded compared with the martensite phase in test solutions. Bainite-microstructure in ferrite-bainite dual-phase steels was preferentially corroded compared with ferrite-phase in CaCl2 and MgCl2 solutions. The corrosion behavior in test solutions in dual-phase steels could be divided into three steps: dissolution in anodic-phase/microstructure, non-uniform corrosion, and localized corrosion. The results indicated that factors such as galvanic coupling between ferrite/martensite, ferrite/bainite, metallic-matrix/inclusion-phases, metallic-matrix/secondary phases, and self-corrosion of each phase and microstructure contributed to the non-uniform and localized corrosion in dual-phase steels.
引用
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页数:13
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