Research on non-equilibrium condensation of supercritical carbon dioxide in sCO2 power systems

Based on the consideration of sustainable development and energy efficient transformation, people propose using renewable energy to upgrade traditional power generation systems. The supercritical carbon dioxide (sCO2) Brayton cycle has a great utilization potentiality in thermodynamic systems, such as solar thermal power generation systems. When the CO2 fluid flows into the compressors of sCO2 power systems, there is a risk of nonequilibrium condensation due to local expansion and acceleration, which seriously threatens the stability of the whole system. The convergent-divergent nozzle is usually used to study non-equilibrium condensation. In this paper, the wet steam model is used to simulate the non-equilibrium condensation of the CO2 fluid near its critical region in a convergent-divergent nozzle. The phase change model and the thermophysical equation of state are verified by experimental data. The non-equilibrium condensation process is analyzed, and the droplet nucleation process and droplet growth process are described. Non-equilibrium condensation releases the latent heat and forms a condensation shock wave. The influences of the shock wave effect on temperature, pressure, and other parameters are discussed. The initial condensation position and critical subcooled temperature under different inlet conditions are analyzed.