Tuning the layer structure of molybdenum trioxide towards high-performance aqueous zinc-ion batteries

被引:11
作者
Tan, Yu [1 ,5 ]
He, Jinjun [3 ]
Wang, Bo [2 ]
Li, Cheng Chao [2 ]
Wang, Taihong [1 ,4 ]
机构
[1] Hunan Univ, Coll Mat Sci & Engn, Changsha 410082, Peoples R China
[2] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China
[3] Sun Yat Sen Univ, Sch Chem, Guangzhou 510275, Peoples R China
[4] Southern Univ Sci & Technol, Dept Elect & Elect Engn, Shenzhen 518055, Peoples R China
[5] Hunan Agr Univ, Coll Chem & Mat Sci, Changsha, Peoples R China
基金
中国国家自然科学基金;
关键词
Molybdenum trioxide; Cathode; Zinc ion batteries; Polyaniline intercalation; Layered structure; CATHODE MATERIAL; HIGH-CAPACITY; INTERCALATION; ALPHA-MOO3; MORPHOLOGY; MOO3;
D O I
10.1016/j.cclet.2022.04.008
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Aqueous zinc-ion batteries (ZIBs) have attracted significant attentions because of low cost and high reli-ability. However, conventional ZIBs are severely limited by the development of high energy density cath-ode materials with reversible Zn2 + insertion/extraction. Herein, a conducting polymer intercalated MoO3 (PMO) with extensively extended interlayer spacing is developed as a high-performance ZIBs cathode material. The interlayer spacing of PMO is prominently increased which results in an improved Zn2 + mo-bility during charge and discharge process. More significantly, the electrochemical results reveals that the intercalation of PANI facilitates the charge storage and reinforces the layered structure of MoO3, leading to a high capacity and good cycling stability. DFT calculation further reveals the intercalation of PANI into MoO3 significantly lower Zn2 + diffusion barrier. Benefit from these advantages, the ZIBs based on PMO electrode delivers a considerable capacity of 157 mAh/g at 0.5 A/g and ameliorative stability with 63.4% capacity retention after 10 0 0 cycles.(c) 2023 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
引用
收藏
页数:6
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