From Forest to Future: Synthesis of Sustainable High Molecular Weight Polyamides Using and Investigating the AROP of β-Pinene Lactam

Polyamides (PA) are among the most essential and versatile polymers due to their outstanding characteristics, for example, high chemical resistance and temperature stability. Furthermore, nature-derived monomers can introduce hard-to-synthesize structures into the PAs for unique polymer properties. Pinene, as one of the most abundant terpenes in nature and its presumable stability-giving bicyclic structure, is therefore highly promising. This work presents simple anionic ring-opening polymerizations of beta-pinene lactam (AROP) in-bulk and in solution. PAs with high molecular weights, suitable for further processing, are produced. Their good mechanical, thermal (T(d)s up to 440 C-degrees), and transparent appearance render them promising high-performance biomaterials. In the following, the suitability of different initiators is discussed. Thereby, it is found that NaH is the most successful for in-bulk polymerization, with a degree of polymerization (DP) of about 322. For solution-AROP, iPrMgCl.LiCl is successfully used for the first time, achieving DPs up to about 163. The obtained PAs are also hot-pressed, and the dynamic mechanical properties are analyzed.