Comparing sources of carbonaceous aerosols during haze and nonhaze periods in two northern Chinese cities

Radiocarbon (14C), stable carbon isotope (13C), and levoglucosan in PM2.5 were measured in two northern Chinese cities during haze events and nonhaze periods in January 2019, to ascertain the sources and their differences in carbonaceous aerosols between the two periods. The contribution of primary vehicle emissions (17.8 +/- 3.7%) to total carbon in Beijing during that haze event was higher than that of primary coal combustion (7.3 +/- 4.2%), and it increased significantly (7.1%) compared to the nonhaze period. The contribution of primary vehicle emissions (4.1 +/- 2.8%) was close to that of primary coal combustion (4.3 +/- 3.3%) during the haze event in Xi'an, and the contribution of primary vehicle emissions decreased by 5.8% compared to the nonhaze period. Primary biomass burning contributed 21.1 +/- 10.5% during the haze event in Beijing and 40.9 +/- 6.6% in Xi'an (with an increase of 3.3% compared with the nonhaze period). The contribution of secondary fossil fuel sources to total secondary organic carbon increased by 29.2% during the haze event in Beijing and by 18.4% in Xi'an compared to the nonhaze period. These results indicate that specific management measures for air pollution need to be strengthened in different Chinese cities in the future, that is, controlling vehicle emissions in Beijing and restricting the use of coal and biomass fuels in winter in Xi'an.